Copper-Catalyzed Direct C-H Trifluoromethylation of Quinones

被引:77
|
作者
Wang, Xi
Ye, Yuxuan
Ji, Guojing
Xu, Yan
Zhang, Songnan
Feng, Jiajie
Zhang, Yan [1 ]
Wang, Jianbo
机构
[1] Peking Univ, BNLMS, Minist Educ, Coll Chem, Beijing 100871, Peoples R China
关键词
CHLOROUS ACID OXIDATION; ARYL BORONIC ACIDS; MEDIATED TRIFLUOROMETHYLATION; EFFICIENT; ALKENES; REAGENT; OXYTRIFLUOROMETHYLATION; ALLYLSILANES; FLUORINATION; ARENES;
D O I
10.1021/ol4016095
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient and practical methodology has been developed to introduce the CF3 group onto quinones through Cu(I)-catalyzed direct C-H trifluoromethylation of quinones.
引用
收藏
页码:3730 / 3733
页数:4
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