Bio-Acrylates Production: Recent Catalytic Advances and Perspectives of the Use of Lactic Acid and Their Derivates

被引：45
|
作者：
Makshina, Ekaterina V. [1 ]
Canadell, Judit [2 ]
van Krieken, Jan [2 ]
Peeters, Elise [1 ]
Dusselier, Michiel [1 ]
Sels, Bert F. [1 ]
机构：
[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, Celestijnenlaan 200F, B-3001 Heverlee, Belgium
[2] Corbion, Cent R&D, Arkelsedijk 46, NL-4206 AC Gorinchem, Netherlands
来源：
CHEMCATCHEM | 2019年 / 11卷 / 01期
基金：
比利时弗兰德研究基金会;
关键词：
GAS-PHASE DEHYDRATION; EXCHANGED BETA-ZEOLITE; METAL-MODIFIED NAY; ACRYLIC-ACID; ALDOL CONDENSATION; METHYL LACTATE; ACETIC-ACID; SUSTAINABLE PRODUCTION; HIGHLY EFFICIENT; UNSATURATED ALDEHYDES;
D O I：
10.1002/cctc.201801494
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The production of drop-in chemicals from bio-based renewable sources is gaining a lot of momentum due to proven negative impact of fossil-based economy on environment and society. In this Review, various bio-derived platform molecules are assessed as renewable alternatives to fossil resources for the catalytic production of acrylates. Acrylic acid and its esters are key building blocks of a large number of high-value oligomers and polymers in the current industry. In spite of the encouraging successes reported on gram or lab-scale, real implementation of bio-based examples remain scarce mainly due to the current high cost and limited availability of the bio-based substrates. As lactic acid and their derivatives are one of the most promising feedstocks for bio-acrylate production, they are the main focus of this Review.
引用
收藏
页码：180 / 201
页数：22
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