(3+2) Cycloadditions of Thiouronium Ylides: A Room-Temperature, One-Pot Approach to Dihydrothiophenes

被引：10

作者：

Neuhaus, James D. ^{[1
]}

Angyal, Peter ^{[1
]}

Oost, Rik ^{[1
]}

Maulide, Nuno ^{[1
]}

机构：

[1] Univ Vienna, Inst Organ Chem, Wahringer Str 38, A-1090 Vienna, Austria

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 83卷 / 04期

关键词：

THIOCARBONYL YLIDES; CONDENSED CHROMONES; CYCLOPROPANATION; DERIVATIVES; MOLECULES; THIOBENZOPHENONE; PHOTOGENERATION; REARRANGEMENT; DIAZOMETHANE; CYCLIZATION;

D O I：

10.1021/acs.joc.7b03255

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A room-temperature (3+2) cycloaddition sequence for the synthesis of highly substituted dihydrothiophene derivatives has been developed. By utilizing structurally unique thiocarbonyl ylides, the reactivity of these traditionally high-energy intermediates can be modulated, enabling a synthetically useful transformation to proceed under mild conditions.

引用

页码：2479 / 2485

页数：7

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