One-pot room-temperature conversion of cyclohexane to adipic acid by ozone and UV light

被引：90
|
作者：
Hwang, Kuo Chu [1 ]
Sagadevan, Arunachalam [1 ]
机构：
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan
来源：
SCIENCE | 2014年 / 346卷 / 6216期
关键词：
CATALYTIC-OXIDATION; BOND; HYDROCARBONS; PHOTOLYSIS; H2O2;
D O I：
10.1126/science.1259684
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Nitric acid oxidation of cyclohexane accounts for similar to 95% of the worldwide adipic acid production and is also responsible for similar to 5 to 8% of the annual worldwide anthropogenic emission of the ozone-depleting greenhouse gas nitrous oxide (N2O). Here we report a N2O-free process for adipic acid synthesis. Treatment of neat cyclohexane, cyclohexanol, or cyclohexanone with ozone at room temperature and 1 atmosphere of pressure affords adipic acid as a solid precipitate. Addition of acidic water or exposure to ultraviolet (UV) light irradiation (or a combination of both) dramatically enhances the oxidative conversion of cyclohexane to adipic acid.
引用
收藏
页码：1495 / 1498
页数：4
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