Activity of different zeolite-supported Ni catalysts for methane reforming with carbon dioxide

被引:106
|
作者
Luengnaruemitchai, Apanee [1 ]
Kaengsilalai, Athiya [1 ]
机构
[1] Chulalongkorn Univ, Petr & Petrochem Coll, Bangkok 10330, Thailand
关键词
CH4; CO2; reforming; Ni; Zeolite; Carbon deposition;
D O I
10.1016/j.cej.2008.05.023
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The catalytic performance of Ni based on various types of zeolites (zeolite A, zeolite X, zeolite Y, and ZSM-5) prepared by incipient wetness impregnation has been investigated for the catalytic carbon dioxide reforming of methane into synthesis gas at 700 degrees C, at atmospheric pressure, and at a CH4/CO2 ratio of 1. It was found that Ni/zeolite Y showed better catalytic performance than the other types of studied zeolites. In addition. the stability of the Ni/zeolite Y was greatly superior to that of the other catalysts. A weight of Ni loading at 7 wt.% showed the best catalytic activity on each zeolite support; however, the 7% Ni catalysts produced a higher amount of coke than that of two other Ni loadings, 3 and 5%. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:96 / 102
页数:7
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