Ultra-stable Ni catalysts for methane reforming by carbon dioxide

被引：59
|
作者：
Tomishige, K [1 ]
Fujimoto, K [1 ]
机构：
[1] Univ Tokyo, Grad Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
来源：
CATALYSIS SURVEYS FROM JAPAN | 1998年 / 2卷 / 01期
关键词：
methane reforming with carbon dioxide; nickel-magnesia solid solution catalyst; long life; carbon deposition; metal-support interaction; inhibition mechanism of carbon formation; effects of noble metals;
D O I：
10.1023/A:1019001702796
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Methane reforming by carbon dioxide has been studied over ultra-stable Ni catalysts. The catalyst was characterized by XRD, IR and TEM and temperature programmed hydrogenation. The nickel-magnesia solid solution catalyst containing low nickel has shown excellent stability (>3000 h) and no carbon deposition in the methane reforming by carbon dioxide. It was also found that the small nickel metal particle interaction with support surface is effective for the inhibition of carbon formation.
引用
收藏
页码：3 / 15
页数：13
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