Synthesis, crystal structure and vibrational spectroscopy of a novel mixed ligands Ni(II) pentaborate:: [Ni(C4H10N2)(C2H8N2)2][B5O6(OH)4]2

被引：57
|
作者：
Liu, ZH [1 ]
Zhang, HH [1 ]
Zhang, WJ [1 ]
机构：
[1] Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 02期
关键词：
borate; hydrothermal synthesis; crystal structure; vibrational spectroscopy; thermal behavior;
D O I：
10.1016/j.ica.2005.10.008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel organic-inorganic hybrid pentaborate [Ni(C4H10N2)(C2H8N2)(2)][B5O6(OH)(4)](2) has been synthesized by hydrothermal reaction and characterized by FT-IR, Raman spectroscopy, elemental analyses and DTA-TGA. Its crystal structure was determined from single crystal X-ray diffraction The structure consists of isolated polyborate anion [B5O6(OH)(4)](-) and nickel complex cation of [Ni(C4H10N2)(C2H8N2)(2)](2+) in which the two kinds of ligands come from the decomposition of triethylenetriamine material. The [B5O6(OH)(4)](-) units are connected to one another through hydrogen bonds, forming a three-dimensional framework with large channel along the a and c axes, in which the templating [Ni(C4H10N2)(C2H8N2)(2)](2+) cations are located. The assignments of the record FT-IR absorption frequencies and Raman shifts were given. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：519 / 524
页数：6
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