Synthesis, crystal structure and vibrational spectroscopy of a novel mixed ligands Ni(II) pentaborate:: [Ni(C4H10N2)(C2H8N2)2][B5O6(OH)4]2

被引：57
|
作者：
Liu, ZH [1 ]
Zhang, HH [1 ]
Zhang, WJ [1 ]
机构：
[1] Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 02期
关键词：
borate; hydrothermal synthesis; crystal structure; vibrational spectroscopy; thermal behavior;
D O I：
10.1016/j.ica.2005.10.008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel organic-inorganic hybrid pentaborate [Ni(C4H10N2)(C2H8N2)(2)][B5O6(OH)(4)](2) has been synthesized by hydrothermal reaction and characterized by FT-IR, Raman spectroscopy, elemental analyses and DTA-TGA. Its crystal structure was determined from single crystal X-ray diffraction The structure consists of isolated polyborate anion [B5O6(OH)(4)](-) and nickel complex cation of [Ni(C4H10N2)(C2H8N2)(2)](2+) in which the two kinds of ligands come from the decomposition of triethylenetriamine material. The [B5O6(OH)(4)](-) units are connected to one another through hydrogen bonds, forming a three-dimensional framework with large channel along the a and c axes, in which the templating [Ni(C4H10N2)(C2H8N2)(2)](2+) cations are located. The assignments of the record FT-IR absorption frequencies and Raman shifts were given. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：519 / 524
页数：6
相关论文
共 50 条
  • [21] Crystal structure of bis(diethylenetriamine)cobalt(II) tetrahydroxypentaborate, [Co(C4H13N3)2][B5O6(OH)4]2
    Liu, ZH
    Zhang, JJ
    Zhang, WJ
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2005, 220 (04): : 555 - 556
  • [22] Crystal structure of diaquabis(ethylenediamino)copper(II) squarate dihydrate, [Cu(C2H8N2)2(H2O)2](C4O4) • 2H2O
    Nuss, Hanne
    Jansen, Martin
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (04): : 773 - 774
  • [23] Synthesis and Crystal Structure of Complex [Cd•(C7H6N2O4S)•(C10H8N4)]•2H2O
    Li, S. -X.
    Liao, B. -L.
    Yang, G. -G.
    Jiang, Y. -M.
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (06) : 926 - 929
  • [24] Synthesis and crystal structure of [Ni(C5H2N2O4)(2,2′-bipy)(H2O)2]•2H2O
    Li, X
    Cao, R
    Sun, DF
    Hong, MC
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 21 (04) : 374 - 377
  • [25] STRUCTURE DETERMINATION ON A TWINNED CRYSTAL OF CESIUM PENTABORATE TETRAHYDRATE, CS[B5O6(OH)4].2H2O
    BEHM, H
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (JUL) : 1114 - 1116
  • [26] Electron Spin Resonance in a Single Crystal of Ni(C2H8N2)2NO2(ClO4)
    Guo, Sheng-Li
    Kong, Chun-Xia
    Tian, Li
    PROCEEDINGS OF THE 2010 INTERNATIONAL CONFERENCE ON APPLICATION OF MATHEMATICS AND PHYSICS, VOL 1: ADVANCES ON SPACE WEATHER, METEOROLOGY AND APPLIED PHYSICS, 2010, : 331 - 338
  • [27] Crystal structure of tetraaqua-(4,4′-bipyridine-κ2N,N′)nickel(II) 2,3-naphthalenedicarboxylate, [Ni(H2O)4(C10H8N2)][C12H6O4]
    Hu, Min
    Zhang, Qiang
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (01): : 155 - 156
  • [28] RUBIDIUM PENTABORATE TETRAHYDRATE, RB[B5O6(OH)4].2H2O
    BEHM, H
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (FEB) : 217 - 220
  • [29] Synthesis and crystal structure of (C3N5H6S)2]UO2(C2O4)2(H2O)]•C2N4H4
    Serezhkina, L. B.
    Virovets, A. V.
    Peresypkina, E. V.
    Medrish, I. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2007, 33 (05) : 371 - 376
  • [30] Synthesis and crystal structure of (C3N5H6S)2[UO2(C2O4)2(H2O)] · C2N4H4
    L. B. Serezhkina
    A. V. Virovets
    E. V. Peresypkina
    I. V. Medrish
    Russian Journal of Coordination Chemistry, 2007, 33 : 371 - 376
12345