LACASSE CATALYZED-SYNTHESIS OF 4,4′-BIPHENYLDIAMINE FROM P-CHLOROANILINE. EVALUATION OF ANTIFUNGAL AND ANTIOXIDANT ACTIVITIES

被引：2

作者：

Campos, Ana M. ^{[1
]}

Mendoza, Leonora ^{[1
]}

Vasquez, Juan ^{[1
]}

Melo, Ricardo ^{[1
]}

Salas, Jennifer ^{[1
]}

Cotoras, Milena ^{[1
]}

机构：

[1] Univ Santiago Chile, Fac Quim & Biol, Casilla 40-Correo 33, Santiago, Chile

来源：

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2016年 / 61卷 / 03期

关键词：

p-chloroaniline; 4,4 '-Biphenyldiamine; laccase; antioxidant activity; antifungal activity; BOTRYTIS-CINEREA; ENZYMATIC-SYNTHESIS; FUNGAL LACCASES; FERULIC ACID; AMINATION; BIOTRANSFORMATION; RESVERATROL; DERIVATIVES; PRODUCTS; CHITOSAN;

D O I：

10.4067/S0717-97072016000300004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Laccase is a copper-containing oxidase that catalyzes reduction of molecular oxygen to water and the oxidation of a phenolic compound. In this paper, laccase was utilized to synthesize 4,4'-Biphenyldiamine using p-chloroaniline as substrate by means of a coupling reaction. The synthesized compound, 4,4'-Biphenyldiamine, presented low antifungal activity against the phytopathogenic fungus Botrytis cinerea, however the antioxidant ability, measurement by ORAC-PGR method, was higher than substrate. This work corresponds to the first report of synthesis 4,4'-Biphenyldiamine, from p-chloroaniline in a lacasse-catalyzed reaction.

引用

页码：3031 / 3033

页数：3

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