LACASSE CATALYZED-SYNTHESIS OF 4,4′-BIPHENYLDIAMINE FROM P-CHLOROANILINE. EVALUATION OF ANTIFUNGAL AND ANTIOXIDANT ACTIVITIES

被引：2
|
作者：
Campos, Ana M. [1 ]
Mendoza, Leonora [1 ]
Vasquez, Juan [1 ]
Melo, Ricardo [1 ]
Salas, Jennifer [1 ]
Cotoras, Milena [1 ]
机构：
[1] Univ Santiago Chile, Fac Quim & Biol, Casilla 40-Correo 33, Santiago, Chile
来源：
JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2016年 / 61卷 / 03期
关键词：
p-chloroaniline; 4,4 '-Biphenyldiamine; laccase; antioxidant activity; antifungal activity; BOTRYTIS-CINEREA; ENZYMATIC-SYNTHESIS; FUNGAL LACCASES; FERULIC ACID; AMINATION; BIOTRANSFORMATION; RESVERATROL; DERIVATIVES; PRODUCTS; CHITOSAN;
D O I：
10.4067/S0717-97072016000300004
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Laccase is a copper-containing oxidase that catalyzes reduction of molecular oxygen to water and the oxidation of a phenolic compound. In this paper, laccase was utilized to synthesize 4,4'-Biphenyldiamine using p-chloroaniline as substrate by means of a coupling reaction. The synthesized compound, 4,4'-Biphenyldiamine, presented low antifungal activity against the phytopathogenic fungus Botrytis cinerea, however the antioxidant ability, measurement by ORAC-PGR method, was higher than substrate. This work corresponds to the first report of synthesis 4,4'-Biphenyldiamine, from p-chloroaniline in a lacasse-catalyzed reaction.
引用
收藏
页码：3031 / 3033
页数：3
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