Facile C-H, C-F, C-CI, and C-C Activation by Oxatitanacyclobutene Complexes

被引：5
|
作者：
Nguyen, Trang T. [1 ]
Bertke, Jeffery A. [1 ]
Gray, Danielle L. [1 ]
Hull, Kami L. [1 ]
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
来源：
ORGANOMETALLICS | 2015年 / 34卷 / 17期
关键词：
ALPHA; BETA-UNSATURATED IMINES; CATALYTIC CARBOAMINATION; HYDROAMINATION CATALYSTS; INSERTION REACTIONS; IMIDO COMPLEX; ALKYNES; TITANIUM; CYCLOADDITION; CYCLIZATION; REACTIVITY;
D O I：
10.1021/acs.organomet.5b00470
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Aryl ketones react readily with oxatitanacydobutenes bearing pentamethylcyclopentadienyl ligands to form unique titanocene complexes resulting from Cp* modification and C-H activation. An intermediate in this reaction is intercepted with various functional groups to form carbonyl insertion, C-F activation, and cyclopropane ring-opening products.
引用
收藏
页码：4190 / 4193
页数：4
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