Facile C-H, C-F, C-CI, and C-C Activation by Oxatitanacyclobutene Complexes

被引：5

作者：

Nguyen, Trang T. ^{[1
]}

Bertke, Jeffery A. ^{[1
]}

Gray, Danielle L. ^{[1
]}

Hull, Kami L. ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

来源：

ORGANOMETALLICS | 2015年 / 34卷 / 17期

关键词：

ALPHA; BETA-UNSATURATED IMINES; CATALYTIC CARBOAMINATION; HYDROAMINATION CATALYSTS; INSERTION REACTIONS; IMIDO COMPLEX; ALKYNES; TITANIUM; CYCLOADDITION; CYCLIZATION; REACTIVITY;

D O I：

10.1021/acs.organomet.5b00470

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aryl ketones react readily with oxatitanacydobutenes bearing pentamethylcyclopentadienyl ligands to form unique titanocene complexes resulting from Cp* modification and C-H activation. An intermediate in this reaction is intercepted with various functional groups to form carbonyl insertion, C-F activation, and cyclopropane ring-opening products.

引用

页码：4190 / 4193

页数：4

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