Synthesis, crystal structure and nonlinear optical property of CsV2O5

被引：6

作者：

Luo, Hong ^{[1
]}

Pan, Jianguo ^{[1
]}

Lou, Bingqian ^{[1
]}

Li, Yuebao ^{[1
]}

Li, Xing ^{[1
]}

Han, Lei ^{[1
]}

机构：

[1] Ningbo Univ, Fac Mat Sci & Engn, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 27卷

基金：

中国国家自然科学基金;

关键词：

Crystal structure; Nonlinear optical material; CsV2O5; CS;

D O I：

10.1016/j.inoche.2012.10.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new nonlinear optical crystal CsV2O5 has been synthesized by solid state reaction and characterized by single-crystal X-ray diffraction and thermogravimetric analysis. The crystal CsV2O5 crystallizes in the orthorhombic system with space Ima2 space group. It is a layered structure that is very flat and strongly parallel to c. The striking structural feature is that the V atom in single crystallographic site has two different valence states (V4+ and V5+). The [V2O5](n) layer consists of corner-linked tetrahedron. The six tetrahedrons lie very nearly in the same z-plane forming almost regular hexagons. The Kurtz powder SHG measurement, using 1064 nm radiation, showed that the second-harmonic generation efficiency of CsV2O5 is about six times that of KDP. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：79 / 81

页数：3

共 50 条

[1] REFINEMENT OF CRYSTAL-STRUCTURE OF CSV2O5
WALTERSSON, K
FORSLUND, B
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (MAR15): : 789 - 793
[2] CRYSTAL STRUCTURE OF REDUCED CESIUM VANADATE, CSV2O5
MUMME, WG
WATTS, JA
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1971, 3 (03) : 319 - &
[3] Electronic and magnetic structure of CsV2O5 -: art. no. 144445
Valentí, R
Saha-Dasgupta, T
[J]. PHYSICAL REVIEW B, 2002, 65 (14): : 1 - 6
[4] Magnetic Couplings in CsV2O5: A New Picture
Saul, A.
Radtke, G.
[J]. PHYSICAL REVIEW LETTERS, 2011, 106 (17)
[5] Synthesis, crystal structure and nonlinear optical property of Rb3V5O14
Pan, Jianguo
Li, Yuebao
Cui, Yuejie
Zhao, Lingyan
Li, Xing
Han, Lei
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (12) : 2759 - 2762
[6] Synthesis, Crystal Structure and Nonlinear Optical Property of RbHgI3
Li, Yanjun
Ding, Yuxun
Li, Yaming
Liu, Hongming
Meng, Xianggao
Cong, Ye
Zhang, Jiang
Li, Xuanke
Chen, Xingguo
Qin, Jingui
[J]. CRYSTALS, 2017, 7 (05):
[7] MAGNETIC-BEHAVIOR OF THE V4+-V4+ PAIR IN THE CSV2O5 COMPOUND
MUR, J
DARRIET, J
[J]. COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II, 1985, 300 (13): : 599 - 602
[8] Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14
Pan, Shilie
Smit, Jared P.
Marvel, Michael R.
Stampler, Evan S.
Haag, Jacob M.
Baek, Jaewook
Halasyamani, P. Shiv
Poeppelmeier, Kenneth R.
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (08) : 2087 - 2091
[9] Synthesis, Crystal Structure, and Nonlinear Optical Property of an Anhydrous Sulfate KTb(SO4)2
Wu, Qi
Yang, Can
Ma, Jie
Liang, Fei
Teng, Chunlin
Du, Yeshuang
[J]. INORGANIC CHEMISTRY, 2021, 60 (19) : 15041 - 15047
[10] Synthesis, Crystal Structure and Nonlinear Optical Property of K2W3SeO12
Huang Yin
Meng Xiang-Gao
Qin Jin-Gui
[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2014, 30 (01) : 179 - 184

← 1 2 3 4 5 →