Synthesis, crystal structure and nonlinear optical property of CsV2O5

被引：6
|
作者：
Luo, Hong [1 ]
Pan, Jianguo [1 ]
Lou, Bingqian [1 ]
Li, Yuebao [1 ]
Li, Xing [1 ]
Han, Lei [1 ]
机构：
[1] Ningbo Univ, Fac Mat Sci & Engn, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 27卷
基金：
中国国家自然科学基金;
关键词：
Crystal structure; Nonlinear optical material; CsV2O5; CS;
D O I：
10.1016/j.inoche.2012.10.023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new nonlinear optical crystal CsV2O5 has been synthesized by solid state reaction and characterized by single-crystal X-ray diffraction and thermogravimetric analysis. The crystal CsV2O5 crystallizes in the orthorhombic system with space Ima2 space group. It is a layered structure that is very flat and strongly parallel to c. The striking structural feature is that the V atom in single crystallographic site has two different valence states (V4+ and V5+). The [V2O5](n) layer consists of corner-linked tetrahedron. The six tetrahedrons lie very nearly in the same z-plane forming almost regular hexagons. The Kurtz powder SHG measurement, using 1064 nm radiation, showed that the second-harmonic generation efficiency of CsV2O5 is about six times that of KDP. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：79 / 81
页数：3
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