Synthesis, crystal structure and nonlinear optical property of Rb3V5O14

被引：7
|
作者：
Pan, Jianguo [1 ]
Li, Yuebao [1 ]
Cui, Yuejie [1 ]
Zhao, Lingyan [1 ]
Li, Xing [1 ]
Han, Lei [1 ]
机构：
[1] Ningbo Univ, Fac Mat Sci & Engn, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2010年 / 183卷 / 12期
基金：
中国国家自然科学基金;
关键词：
Crystal structure; Nonlinear optical material; Rb3V5O14; OXIDES;
D O I：
10.1016/j.jssc.2010.09.017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new nonlinear optical crystal Rb3V5O14 has been synthesized by solid state reaction and characterized by single-crystal X-ray diffraction, IR and thermogravimetric analysis. The crystal Rb3V5O14 crystallizes in the trigonal system with space P31m (No. 157), a=b=8.7134(12) angstrom, c=5.2807(11) angstrom and alpha=90 degrees, beta=90 degrees, gamma=120 degrees, Z=1, rho=3.516 g/cm(3). It is a layered structure that is very flat and strongly parallel to c. The V5O14 layer structure consists of corner-linked square and triangular pyramids. The layers are separated by Rb+ ions, which fit equally well on the V5O14 layer. The Kurtz powder SHG measurement, using 1064 nm radiation, showed that the second-harmonic generation efficiency of Rb3V5O14 is about two times that of KDP. (C) 2010 Elsevier Inc. All rights reserved.
引用
收藏
页码：2759 / 2762
页数：4
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