Synthesis of Thioethers and Thioesters with Alkyl Arylsulfinates as the Sulfenylation Agent under Metal-Free Conditions

被引：22

作者：

Li, Yahui ^{[1
]}

Zhu, Fengxiang ^{[1
]}

Wang, Zechao ^{[1
]}

Wu, Xiao-Feng ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 24期

关键词：

arylsulfinates; carbonylation; domino reactions; green chemistry; sulfenylation agent; CATALYZED REGIOSELECTIVE SULFENYLATION; ARYLSULFONYL CHLORIDES; DIARYL DISULFIDES; DIRECT THIOLATION; SULFUR-DIOXIDE; BOND FORMATION; C-S; INDOLES; 3-SULFENYL; RADICALS;

D O I：

10.1002/asia.201601376

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study on the coupling of cycloalkanes with alkyl arylsulfinates has been performed. Using iodine as the catalyst, through Csp3 -H bond activation and sulfinates reduction, a wide range of thioethers were produced in moderate to high yields. Additionally, various thiocarboxylic esters can also be produced by simply performing the reaction under CO pressure. Notably, this is the first report in which alkyl arylsulfinates were used as sulfenylation agents in a cross-coupling transformation.

引用

页码：3503 / 3507

页数：5

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