Metal-free thioesterification of amides generating acyl thioesters

被引：15
|
作者：
Wang, Qun [1 ]
Liu, Long [2 ]
Dong, Jianyu [3 ]
Tian, Zhibin [2 ]
Chen, Tieqiao [1 ,2 ]
机构：
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
[2] Hainan Univ, Coll Mat & Chem Engn, Minist Educ Adv Mat Trop Isl Resources, Key Lab, Haikou 570228, Hainan, Peoples R China
[3] Hunan First Normal Univ, Dept Educ Sci, Changsha 410205, Hunan, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2019年 / 43卷 / 24期
关键词：
N-C CLEAVAGE; PALLADIUM-CATALYZED THIOCARBONYLATION; HIGHLY REGIOSELECTIVE THIOCARBONYLATION; ELECTRONICALLY-ACTIVATED AMIDES; INTERMOLECULAR RADICAL REACTION; BOND-CLEAVING ALKYLATION; EFFICIENT SYNTHESIS; SECONDARY AMIDES; CARBON-MONOXIDE; DECARBONYLATIVE SILYLATION;
D O I：
10.1039/c9nj01748h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A base-initiated thioesterification of amides with various thiols is reported. This reaction can take place efficiently under metal-free and air-atmospheric conditions, and provides a facile and practically useful approach to the synthesis of valuable acyl thioesters.
引用
收藏
页码：9384 / 9388
页数：5
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