Highly enantioselective Henry reaction catalyzed by chiral tridentate heteroorganic ligands

被引：33
|
作者：
Rachwalski, Michal [1 ,2 ]
Lesniak, Stanislaw [1 ]
Sznajder, Ewelina [1 ]
Kielbasinski, Piotr [2 ]
机构：
[1] Univ Lodz, Dept Organ & Appl Chem, PL-90136 Lodz, Poland
[2] Polish Acad Sci, Ctr Mol & Macromol Studies, Dept Heteroorgan Chem, PL-90363 Lodz, Poland
来源：
TETRAHEDRON-ASYMMETRY | 2009年 / 20卷 / 13期
关键词：
NITROALDOL REACTION; COMPLEXES;
D O I：
10.1016/j.tetasy.2009.06.015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New tridentate enantiomerically pure heteroatom catalysts, containing hydroxyl, sulfinyl and amino groups, proved to be highly efficient in the enantioselective nitroaldol (Henry) reaction to give the desired adducts in very high yields (Lip to 90%) and with ees up to 98%. The influence of the stereogenic centres located on the sulfinyl sulfur atom and in the amine moiety is also discussed. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1547 / 1549
页数：3
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