Enantioselective nitroaldol (Henry) reaction catalyzed by chiral Schiff-base ligands

被引:31
|
作者
Colak, Mehmet [1 ]
Demirel, Nadir [1 ]
机构
[1] Dicle Univ, Dept Chem, Fac Sci, TR-21280 Diyarbakir, Turkey
关键词
D O I
10.1016/j.tetasy.2008.02.005
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Chiral Schiff-bases 2, 3, 4 and 5 were designed for the enantioselective nitroaldol (Henry) reaction. The highest enantioselectivity was observed for ligand 4 (82% ee) when CH2Cl2 was used as a solvent. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:635 / 639
页数:5
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