First palladium-catalyzed aminations of aryl chlorides

被引:99
|
作者
Beller, M
Riermeier, TH
Reisinger, CP
Herrmann, WA
机构
[1] Anorganisch-chemisches Institut, TU München
关键词
D O I
10.1016/S0040-4039(97)00289-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The palladium-catalyzed coupling reaction of aryl chlorides with various amines has been studied for the first rime. Crucial for the success of this C-N bond forming reaction is the use of potassium tertbutoxide as base. Turn over numbers up to 900 and yields up to 80 % have been obtained. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:2073 / 2074
页数:2
相关论文
共 50 条
  • [31] Palladium-Catalyzed Amination of Aryl Chlorides and Bromides with Ammonium Salts
    Green, Rebecca A.
    Hartwig, John F.
    ORGANIC LETTERS, 2014, 16 (17) : 4388 - 4391
  • [32] Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
    Shen, Xiaoqiang
    Hyde, Alan M.
    Buchwald, Stephen L.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (40) : 14076 - 14078
  • [33] Palladium-Catalyzed Indole, Pyrrole, and Furan Arylation by Aryl Chlorides
    Nadres, Enrico T.
    Lazareva, Anna
    Daugulis, Olafs
    JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (02): : 471 - 483
  • [34] PALLADIUM-CATALYZED CROSS-COUPLING OF ARYL CHLORIDES WITH ARYLSILATRANES
    Yamamoto, Yutaro
    Baralle, Alexandre
    Godefroy, Anais
    Murakami, Kei
    Yorimitsu, Hideki
    Osuka, Atsuhiro
    HETEROCYCLES, 2017, 95 (01) : 568 - 574
  • [35] Versatile palladium-catalyzed arylation of organomanganese chlorides by aryl bromides
    Riguet, E
    Alami, M
    Cahiez, G
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 624 (1-2) : 376 - 379
  • [36] Improved Palladium-Catalyzed Sonogashira Coupling Reactions of Aryl Chlorides
    Torborg, Christian
    Huang, Jun
    Schulz, Thomas
    Schaeffner, Benjamin
    Zapf, Alexander
    Spannenberg, Anke
    Boerner, Armin
    Beller, Matthias
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (06) : 1329 - 1336
  • [37] PALLADIUM-CATALYZED VINYLATION OF ARYL CHLORIDES - CHELATE EFFECT IN CATALYSIS
    BENDAVID, Y
    PORTNOY, M
    GOZIN, M
    MILSTEIN, D
    ORGANOMETALLICS, 1992, 11 (06) : 1995 - 1996
  • [38] A new improved catalyst for the palladium-catalyzed amination of aryl chlorides
    Ehrentraut, A
    Zapf, A
    Beller, M
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 182 (01) : 515 - 523
  • [39] Palladium-catalyzed deacetonative coupling of aryl propargylic alcohols with aryl chlorides in water
    Chang, Feng
    Liu, Yanping
    SYNTHETIC COMMUNICATIONS, 2017, 47 (10) : 961 - 967
  • [40] Palladium-catalyzed Heck coupling of 2-vinylpyridine with aryl chlorides
    Li, Ming
    Hua, Ruimao
    APPLIED ORGANOMETALLIC CHEMISTRY, 2008, 22 (07) : 397 - 401