Synthesis of new type of water-soluble hybrid phosphine-phosphonate ligands

被引：2
|
作者：
Ma, XB
Fu, XK [1 ]
Li, LQ
机构：
[1] SW China Normal Univ, Coll Chem & Chem Engn, Chongqing 400715, Peoples R China
[2] Sichuan Univ, Dept Chem, Chengdu 610064, Peoples R China
来源：
SYNTHETIC COMMUNICATIONS | 2002年 / 32卷 / 04期
关键词：
D O I：
10.1081/SCC-120002399
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Phosphonate-functionalized phosphine ligands (2a-d) and their water-soluble di-sodium salts Na2O3PCH2CH2NR1 (CH2CH2NR2)(n)R-3 (3a-d) were prepared by a new route using bis(hydroxymethyl)diphenylphosphonium chloride with 2-aminoethylphosphonic acid and its N-substituted compounds H2O3PCH2CH2NR1(CH2CH2NR2)(n)R-3 (1a-d) under mild conditions at 60-70degreesC and without special reagents. The solubilities of 3a-d in water at 25 degreesC were also measured and compared.
引用
收藏
页码：539 / 546
页数：8
相关论文
共 50 条
  • [41] SYNTHESIS OF NEW WATER-SOLUBLE CHOLESTEROL DERIVATIVES
    Schmidt, Florian
    Spoerner, Michael
    Kalbitzer, Hans Robert
    Koenig, Burkhard
    SYNTHETIC COMMUNICATIONS, 2011, 41 (19) : 2876 - 2887
  • [42] A novel chiral water-soluble phosphine ligand based on a water-soluble acrylic acid salt
    Malmstrom, T
    Andersson, C
    CHEMICAL COMMUNICATIONS, 1996, (10) : 1135 - 1136
  • [43] In vitro antitumor activity of water-soluble copper(I) complexes with diimine and monodentate phosphine ligands
    Porchia, Marina
    Tisato, Francesco
    Zancato, Mirella
    Gandin, Valentina
    Marzano, Cristina
    ARABIAN JOURNAL OF CHEMISTRY, 2020, 13 (01) : 998 - 1010
  • [44] Mixed-ligand strategy for synthesizing water-soluble chiral gold clusters with phosphine ligands
    Ajioka, Hiyori
    Komada, Mayuko
    Yao, Hiroshi
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, 24 (47) : 29223 - 29231
  • [45] Synthesis and characterization of water-soluble diphosphine ligands and their platinum complexes.
    Hopkins, SL
    Schreiner, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U997 - U997
  • [46] Synthesis of water-soluble aminosulfonamide ligands and their application in enantioselective transfer hydrogenation
    Bubert, C
    Blacker, J
    Brown, SM
    Crosby, J
    Fitzjohn, S
    Muxworthy, JP
    Thorpe, T
    Williams, JMJ
    TETRAHEDRON LETTERS, 2001, 42 (24) : 4037 - 4039
  • [47] NEW WATER-SOLUBLE PHOSPHONATE AND POLYCARBOXYLATE COMPLEXANTS FOR ENHANCED F-ELEMENT SEPARATIONS
    NASH, KL
    RICKERT, PG
    LESSMAN, E
    MENDOZA, M
    FEIL, J
    SULLIVAN, JC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 177 - IEC
  • [48] ORGN 637-Palladium catalyzed carbonylation with neopentyl phosphine and water-soluble phosphine ligands to promote activation of aryl halides
    Brown, William S.
    Shaughnessy, Kevin H.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 235
  • [49] FORMATION AND CATALYTIC PROPERTIES OF WATER-SOLUBLE PHOSPHINE COMPLEXES
    JOO, F
    BECK, MT
    REACTION KINETICS AND CATALYSIS LETTERS, 1975, 2 (03): : 257 - 263
  • [50] PTABS: A Unique Water-Soluble π-Acceptor Caged Phosphine
    Sahu, Rajesh
    Kapdi, Anant R.
    SYNLETT, 2023, 34 (08) : 912 - 930
12345