Effect of the resin viscosity on the writing properties of two-photon polymerization

被引：46

作者：

Zandrini, T. ^{[1
]}

Liaros, N. ^{[2
]}

Jiang, L. J. ^{[3
]}

Lu, Y. F. ^{[3
]}

Fourkas, J. T. ^{[2
,4
]}

Osellame, R. ^{[1
]}

Baldacchini, T. ^{[5
]}

机构：

[1] Politecn Milan, Ist Foton & Nanotecnol, Dipartimento Fis, CNR, I-20133 Milan, Italy

[2] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

[3] Univ Nebraska, Dept Elect Engn, Lincoln, NE 68588 USA

[4] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA

[5] Chapman Univ, Schmid Coll Sci & Technol, Orange, CA 92866 USA

来源：

OPTICAL MATERIALS EXPRESS | 2019年 / 9卷 / 06期

基金：

欧盟地平线“2020”; 美国国家科学基金会;

关键词：

FREE-RADICAL POLYMERIZATION; FEMTOSECOND LASER; PHOTOPOLYMERIZATION KINETICS; 3-DIMENSIONAL MICROFABRICATION; STEREOLITHOGRAPHY; INHIBITION; RESOLUTION; INITIATORS; POLYMERS; MONOMERS;

D O I：

10.1364/OME.9.002601

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

While the role of resin viscosity has been largely studied for stereolithography, where a very low viscosity material is preferred, an extensive study of its microscale counterpart, two-photon polymerization, is still lacking. In the present work, we tried to fill the gap by correlating directly the properties of the features produced by two-photon polymerization with the viscosity of four acrylate materials, prepared by mixing two monomers with very different viscosity, and a constant quantity of photoinitiator. Linewidth, polymerization and damage thresholds, dynamic range, and fabrication resolution have been object of investigation in our experiments. (C) 2019 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

引用

页码：2601 / 2616

页数：16

共 50 条

[1] Direct Writing of Photonic Structures by Two-Photon Polymerization
Li, Yan
Liu, ZhaoPei
Cui, HaiBo
Xiao, Yun-Feng
Yang, Hong
Gong, Qihuang
[J]. PROGRESS IN ULTRAFAST LASER MODIFICATIONS OF MATERIALS, 2013, 8
[2] Direct Writing Target Structures by Two-Photon Polymerization
Jiang, L. J.
Campbell, J. H.
Lu, Y. F.
Bernat, T.
Petta, N.
[J]. FUSION SCIENCE AND TECHNOLOGY, 2016, 70 (02) : 295 - 309
[3] Enhanced adhesion in two-photon polymerization direct laser writing
Izard, A. G.
Garcia, E. P.
Dixon, M.
Potma, E. O.
Baldacchini, T.
Valdevit, L.
[J]. AIP ADVANCES, 2020, 10 (04)
[4] Acrylic-based resin with favorable properties for three-dimensional two-photon polymerization
Baldacchini, T
LaFratta, CN
Farrer, RA
Teich, MC
Saleh, BEA
Naughton, MJ
Fourkas, JT
[J]. JOURNAL OF APPLIED PHYSICS, 2004, 95 (11) : 6072 - 6076
[5] Two-photon polymerization of an epoxy-acrylate resin material system
Winfield, R. J.
O'Brien, S.
[J]. APPLIED SURFACE SCIENCE, 2011, 257 (12) : 5389 - 5392
[6] Feature size reduction in two-photon polymerization by optimizing resin composition
Consoli, Pedro M.
Otuka, Adriano J. G.
Balogh, Debora T.
Mendonca, Cleber R.
[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2018, 56 (16) : 1158 - 1163
[7] Direct laser writing of whispering gallery microcavities by two-photon polymerization
Liu, Zhao-Pei
Li, Yan
Xiao, Yun-Feng
Li, Bei-Bei
Jiang, Xue-Feng
Qin, Yi
Feng, Xiao-Bo
Yang, Hong
Gong, Qihuang
[J]. APPLIED PHYSICS LETTERS, 2010, 97 (21)
[8] Two-photon photoinitiated polymerization
Belfield, KD
Schafer, KJ
[J]. PHOTOINITIATED POLYMERIZATION, 2003, 847 : 464 - 481
[9] TWO-PHOTON INITIATORS OF POLYMERIZATION
Wrzyszczynski, Andrzej
[J]. POLIMERY, 2010, 55 (03) : 167 - 171
[10] Two-Photon Polymerization of Polydiacetylene
Shusterman, Olga
Berman, Amir
Golan, Yuval
Horovitz, Baruch
Zeiri, Leila
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (05): : 1273 - 1276

← 1 2 3 4 5 →