Copolymerization of vinyl chloride with 1-vinyl-4,5,6,7-tetrahydroindole and 2-methyl-5-vinylpyridine

被引：2
|
作者：
Shaglaeva, N. S. [1 ]
Lebedeva, O. V. [2 ]
Pozhidaev, Yu. N. [2 ]
Sultangareev, R. G. [1 ]
Markova, M. V. [1 ]
Salaurov, V. N. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Favorskii Inst Chem, Irkutsk 664033, Russia
[2] Irkutsk State Tech Univ, Irkutsk 664074, Russia
来源：
POLYMER SCIENCE SERIES B | 2008年 / 50卷 / 11-12期
基金：
俄罗斯基础研究基金会;
关键词：
2-methyl-5-vinylpyridine - Charged units - Dehydrochlorination - Hydrogen atoms - Hydrogen chloride - Radical copolymerization - Vinyl chlorides - Vinylpyridine;
D O I：
10.1134/S1560090408110043
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The radical copolymerization of vinyl chloride with 2-methyl-5-vinylpyridine and 1-vinyl-4,5,6,7-tetrahydroindole is accompanied by dehydrochlorination. In the vinyl chloride-2-methyl-5-vinylpyridine system, the evolved hydrogen chloride interacts with a pyridine hydrogen atom to give charged units of a heterocycle. In the vinyl chloride-1-vinyl-4,5,6,7-tetrahydroindole system, the hydrogen chloride being formed initiates the cationic dimerization of a nitrogen-containing monomer. The synthesized copolymers based on vinyl chloride surpass the commercial poly(vinyl chloride) in terms of thermal stability and solubility in organic solvents.
引用
收藏
页码：315 / 320
页数：6
相关论文
共 50 条
  • [41] PYRROLES FROM KETOXYMES AND ACETYLENE .8. SYNTHESIS OF 4,5,6,7-TETRAHYDROINDOLE AND ITS 1-VINYL DERIVATIVE
    MIKHALEVA, AI
    TROFIMOV, BA
    VASILYEV, AN
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1979, (02): : 197 - 199
  • [42] PHARMACOLOGICAL PROPERTIES OF SOME 2-METHYL-3-CARBOY-4,5,6,7-TETRAHYDROINDOLE DERIVATIVES
    SHADURSKAYA, SK
    KHOMENKO, AI
    NEKRASHEVICH, AI
    FARMAKOLOGIYA I TOKSIKOLOGIYA, 1977, 40 (02): : 177 - 181
  • [43] THE COPOLYMERIZATION OF DIVINYL SULFIDE WITH 4-VINYLPYRIDINE AND 2-METHYL-5-VINYLPYRIDINE
    Shaglaeva, N. S.
    Bayandin, V. V.
    Multyev, P. V.
    IZVESTIYA VUZOV-PRIKLADNAYA KHIMIYA I BIOTEKHNOLOGIYA, 2014, (04): : 37 - 40
  • [44] Unexpected annelation of 4,5,6,7-tetrahydroindole with 1-benzoyli-2-phenylacetylene
    Sobenina, LN
    Mikhaleva, AL
    Ushakov, IA
    Elokhina, VN
    Trofimov, BA
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 2003, (08): : 1269 - 1270
  • [45] From 4,5,6,7-tetrahydroindole to functionalized furan-2-one-4,5,6,7-tetrahydroindole-cyclobutene sequence in two steps
    Sobenina, Lyubov N.
    Stepanova, Zinaida V.
    Ushakov, Igor' A.
    Mikhaleva, Al'bina I.
    Tomilin, Denis N.
    Kazheva, Ol'ga N.
    Alexandrov, Grigorii G.
    Dyachenko, Oleg A.
    Trofimov, Boris A.
    TETRAHEDRON, 2011, 67 (26) : 4832 - 4837
  • [46] OLIGOMERIZATION OF 1-VINYL-4,5,6,7-TETRAHYDROINDOL UNDER THE ACTION OF METALLIC SODIUM
    TROFIMOV, BA
    MOROZOVA, LV
    BRODSKAYA, EI
    MIKHALEVA, AI
    MARKOVA, MV
    TORYASHINOVA, DSD
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1989, 31 (12): : 897 - 902
  • [47] A Catalyst for the selective dehydrogenation of 4,5,6,7-tetrahydroindole into indole
    B. A. Trofimov
    A. I. Mikhaleva
    E. Yu. Schmidt
    N. I. Protsuk
    A. V. Ivanov
    O. A. Ryapolov
    Doklady Chemistry, 2011, 437 : 95 - 97
  • [48] A Catalyst for the selective dehydrogenation of 4,5,6,7-tetrahydroindole into indole
    Trofimov, B. A.
    Mikhaleva, A. I.
    Schmidt, E. Yu.
    Protsuk, N. I.
    Ivanov, A. V.
    Ryapolov, O. A.
    DOKLADY CHEMISTRY, 2011, 437 : 95 - 97
  • [49] Unexpected 1:2 Annelation of 4,5,6,7-Tetrahydroindole with 1-Benzoyl-2-phenylacetylene
    L. N. Sobenina
    A. I. Mikhaleva
    I. A. Ushakov
    V. N. Elokhina
    B. A. Trofimov
    Chemistry of Heterocyclic Compounds, 2003, 39 (8) : 1115 - 1116
  • [50] PYRROLES FROM KETOXIMES AND ACETYLENE .2. FULL HYDROGENATION OF 4,5,6,7-TETRAHYDROINDOLE AND ITS N-VINYL DERIVATIVE
    TROFIMOV, BA
    KOROSTOVA, SY
    BALABANOVA, LN
    MIKHALYOVA, AI
    VASILYEV, AN
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1978, (03): : 347 - 349
12345