Copolymerization of vinyl chloride with 1-vinyl-4,5,6,7-tetrahydroindole and 2-methyl-5-vinylpyridine

被引：2

作者：

Shaglaeva, N. S. ^{[1
]}

Lebedeva, O. V. ^{[2
]}

Pozhidaev, Yu. N. ^{[2
]}

Sultangareev, R. G. ^{[1
]}

Markova, M. V. ^{[1
]}

Salaurov, V. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Favorskii Inst Chem, Irkutsk 664033, Russia

[2] Irkutsk State Tech Univ, Irkutsk 664074, Russia

来源：

POLYMER SCIENCE SERIES B | 2008年 / 50卷 / 11-12期

基金：

俄罗斯基础研究基金会;

关键词：

2-methyl-5-vinylpyridine - Charged units - Dehydrochlorination - Hydrogen atoms - Hydrogen chloride - Radical copolymerization - Vinyl chlorides - Vinylpyridine;

D O I：

10.1134/S1560090408110043

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radical copolymerization of vinyl chloride with 2-methyl-5-vinylpyridine and 1-vinyl-4,5,6,7-tetrahydroindole is accompanied by dehydrochlorination. In the vinyl chloride-2-methyl-5-vinylpyridine system, the evolved hydrogen chloride interacts with a pyridine hydrogen atom to give charged units of a heterocycle. In the vinyl chloride-1-vinyl-4,5,6,7-tetrahydroindole system, the hydrogen chloride being formed initiates the cationic dimerization of a nitrogen-containing monomer. The synthesized copolymers based on vinyl chloride surpass the commercial poly(vinyl chloride) in terms of thermal stability and solubility in organic solvents.

引用

页码：315 / 320

页数：6

共 50 条

[11] Dehydrochlorination in the copolymerization ofN-vinyl-4,5,6,7-tetrahydroindole with vinyl chloride or vinylidene dichloride
N. S. Shaglaeva
A. I. Mikhaleva
G. I. Sarapulova
O. V. Lebedeva
A. K. Khaliullin
G. A. Zavarzina
A. N. Volkov
Russian Chemical Bulletin, 1997, 46 : 2149 - 2150
[12] Dehydrochlorination in the copolymerization of N-vinyl-4,5,6,7-tetrahydroindole with vinyl chloride or vinylidene dichloride
Shaglaeva, NS
Mikhaleva, AI
Sarapulova, GI
Lebedeva, OV
Khaliullin, AK
Zavarzina, GA
Volkov, AN
RUSSIAN CHEMICAL BULLETIN, 1997, 46 (12) : 2149 - 2150
[13] 1-Vinyl-1,2,4-triazole in copolymerization reaction with 1-vinyl-4,5,6,7-tetrahydroindole: synthesis and properties of copolymers
Ermakova, T. G.
Kuznetsova, N. P.
Pozdnyakov, A. S.
Larina, L. I.
Korzhova, S. A.
Mazyar, I. V.
Shcherbakova, V. S.
Ivanov, A. V.
Mikhaleva, A. I.
Prozorova, G. F.
RUSSIAN CHEMICAL BULLETIN, 2016, 65 (02) : 485 - 489
[14] Copolymerization of N-Vinyl-4,5,6,7-tetrahydroindole with Acrylamide
O. V. Lebedeva
N. S. Shaglaeva
L. V. Kanitskaya
G. A. Pirogova
S. V. Fedorov
A. I. Mikhaleva
A. K. Khaliullin
Russian Journal of Applied Chemistry, 2001, 74 : 353 - 354
[15] Copolymerization of N-vinyl-4,5,6,7-tetrahydroindole with acrylamide
Lebedeva, O.V.
Shaglaeva, N.S.
Kanitskaya, L.V.
Pirogova, G.A.
Fedorov, S.V.
Mikhaleva, A.I.
Khaliullin, A.K.
1600, Maik Nauka-Interperiodica Publishing (74):
[16] Copolymerization of N-vinyl-4,5,6,7-tetrahydroindole with acrylamide
Lebedeva, OV
Shaglaeva, NS
Kanitskaya, LV
Pirogova, GA
Fedorov, SV
Mikhaleva, AI
Khaliullin, AK
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2001, 74 (02) : 353 - 354
[17] Synthesis and properties of copolymers of 1-vinyl-4,5,6,7-tetrahydroindole with maleic acid
Danilovtseva, EN
Annenkov, VV
Mikhaleva, AI
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1998, 40 (02): : 366 - 368
[18] COPOLYMERIZATION OF N-VINYL-4,5,6,7-TETRAHYDROINDOLE WITH ETHANOLAMINE VINYL ETHER
MOROZOVA, LV
MIKHALEVA, AI
MYACHINA, GF
JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1987, 60 (05): : 1126 - 1129
[19] COPOLYMERIZATION OF N-VINYL-4,5,6,7-TETRAHYDROINDOLE WITH ETHANOLAMINE VINYL ETHER.
Morozova, L.V.
Mikhaleva, A.I.
Myachina, G.F.
1600, (60):
[20] Synthesis and polyelectrolyte properties of carboxyl-containing copolymers of 1-vinyl-4,5,6,7-tetrahydroindole
Annenkov, VV
Lebedeva, OV
Danilovtseva, EN
Mikhaleva, AI
POLYMER SCIENCE SERIES B, 2001, 43 (9-10) : 247 - 250

← 1 2 3 4 5 →