Copolymerization of vinyl chloride with 1-vinyl-4,5,6,7-tetrahydroindole and 2-methyl-5-vinylpyridine

被引：2
|
作者：
Shaglaeva, N. S. [1 ]
Lebedeva, O. V. [2 ]
Pozhidaev, Yu. N. [2 ]
Sultangareev, R. G. [1 ]
Markova, M. V. [1 ]
Salaurov, V. N. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Favorskii Inst Chem, Irkutsk 664033, Russia
[2] Irkutsk State Tech Univ, Irkutsk 664074, Russia
来源：
POLYMER SCIENCE SERIES B | 2008年 / 50卷 / 11-12期
基金：
俄罗斯基础研究基金会;
关键词：
2-methyl-5-vinylpyridine - Charged units - Dehydrochlorination - Hydrogen atoms - Hydrogen chloride - Radical copolymerization - Vinyl chlorides - Vinylpyridine;
D O I：
10.1134/S1560090408110043
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The radical copolymerization of vinyl chloride with 2-methyl-5-vinylpyridine and 1-vinyl-4,5,6,7-tetrahydroindole is accompanied by dehydrochlorination. In the vinyl chloride-2-methyl-5-vinylpyridine system, the evolved hydrogen chloride interacts with a pyridine hydrogen atom to give charged units of a heterocycle. In the vinyl chloride-1-vinyl-4,5,6,7-tetrahydroindole system, the hydrogen chloride being formed initiates the cationic dimerization of a nitrogen-containing monomer. The synthesized copolymers based on vinyl chloride surpass the commercial poly(vinyl chloride) in terms of thermal stability and solubility in organic solvents.
引用
收藏
页码：315 / 320
页数：6
相关论文
共 50 条
  • [1] Copolymerization of vinyl chloride with 1-vinyl-4,5,6,7-tetrahydroindole and 2-methyl-5-vinylpyridine
    N. S. Shaglaeva
    O. V. Lebedeva
    Yu. N. Pozhidaev
    R. G. Sultangareev
    M. V. Markova
    V. N. Salaurov
    Polymer Science Series B, 2008, 50 : 315 - 320
  • [2] Copolymerization of 1-vinyl-4,5,6,7-tetrahydroindole with styrene
    Danilovtseva, EN
    Annenkov, VV
    Domnina, ES
    Mikhaleva, AI
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1996, 38 (11): : 1925 - 1927
  • [3] Copolymerization of 1-Vinyl-4,5,6,7-tetrahydroindole with Vinyl Chloride in the Presence of a Radical Initiator
    N. S. Shaglaeva
    O. V. Lebedeva
    A. I. Mikhaleva
    G. A. Pirogova
    R. G. Sultangareev
    N. N. Chipanina
    G. A. Gavrilova
    Russian Journal of Applied Chemistry, 2002, 75 : 1462 - 1464
  • [4] Copolymerization of 1-vinyl-4,5,6,7-tetrahydroindole with vinyl chloride in the presence of a radical initiator
    Shaglaeva, NS
    Lebedeva, OV
    Mikhaleva, AI
    Pirogova, GA
    Sultangareev, RG
    Chipanina, NN
    Gavrilova, GA
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2002, 75 (09) : 1462 - 1464
  • [5] ELECTROPHILIC ADDITION OF PHENOLS TO 1-VINYL-4,5,6,7-TETRAHYDROINDOLE
    MARKOVA, MV
    MIKHALEVA, AI
    SIGALOV, MV
    MOROZOVA, LV
    ALIEV, IA
    TROFIMOV, BA
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1989, (05): : 604 - 606
  • [6] Dimerization of 1-vinyl-4,5,6,7-tetrahydroindole in the presence of acids
    Morozova, LV
    Mikhaleva, AI
    Markova, MV
    Sobenina, LN
    Trofimov, BA
    RUSSIAN CHEMICAL BULLETIN, 1996, 45 (02) : 407 - 409
  • [7] AN UNEXPECTED MODE OF CATIONIC OLIGOMERIZATION OF 1-VINYL-4,5,6,7-TETRAHYDROINDOLE
    TROFIMOV, BA
    MOROZOVA, LV
    SIGALOV, MV
    MIKHALEVA, AI
    MARKOVA, MV
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1987, 188 (10): : 2251 - 2257
  • [8] Copolymerization of vinyl chloride with 2-methyl-5-vinylpyridine
    Lebedeva, OV
    Shaglaeva, NS
    Pirogova, GA
    Zavarzina, GA
    Volkov, AN
    Khaliullin, AK
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2000, 73 (08) : 1475 - 1476
  • [9] DIMERIZATION OF 1-VINYL-4,5,6,7-TETRAHYDROINDOLE UNDER THE ACTION OF HCL
    TROFIMOV, BA
    MIKHALEVA, AI
    MOROZOVA, LV
    VASILYEV, AN
    SIGALOV, MV
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1983, (02): : 269 - 270
  • [10] 1-Vinyl-1,2,4-triazole in copolymerization reaction with 1-vinyl-4,5,6,7-tetrahydroindole: synthesis and properties of copolymers
    T. G. Ermakova
    N. P. Kuznetsova
    A. S. Pozdnyakov
    L. I. Larina
    S. A. Korzhova
    I. V. Mazyar
    V. S. Shcherbakova
    A. V. Ivanov
    A. I. Mikhaleva
    G. F. Prozorova
    Russian Chemical Bulletin, 2016, 65 : 485 - 489
12345