Syntheses, structures, and magnetic properties of manganese-lanthanide hexanuclear complexes

被引：30

作者：

Shiga, Takuya ^{[1
]}

Hoshino, Norihisa ^{[1
]}

Nakano, Motohiro ^{[2
]}

Nojiri, Hiroyuki ^{[3
]}

Oshio, Hiroki ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

[2] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[3] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 14-15期

关键词：

magnetism; lanthanide; manganese; Schiff-base;

D O I：

10.1016/j.ica.2008.03.096

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of manganese acetate and lanthanide acetate with Schiff-base ligands (H(3)beemp = 2,6-bis[((2(2-hydroxyethoxy)ethyl)imino)methyl]-4-methylphenol) yielded hexanuclear clusters of [ Mn(4)(III)Ln(2)(III)(mu(3)-O)(2)(Hbeemp)(2)(OAc)(8)(mu(3)-OMe)(2)(H(2)O)(2)] center dot C(8)H(17)OH (Ln = Gd, Tb, and Y for 1, 2, and 3, respectively). Magnetic susceptibility measurements revealed that the mixed spin systems of 1 and 2 showed ferrimagnetic behavior, while antiferromagnetic interactions were operative among Mn(3+) ions in 3. Ac magnetic susceptibility measurements for 2 showed frequency dependent in-and out-of-phase signals, confirming slow magnetic relaxation of spin reorientations. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：4113 / 4117

页数：5

共 50 条

[31] Syntheses, structures and magnetic properties of the lanthanide complexes of the pyrimidyl-substituted nitronyl nitroxide radical
Wang, Jian
Miao, Hao
Xiao, Zhao-Xin
Zhou, Yan
Deng, Lin-Dan
Zhang, Yi-Quan
Wang, Xin-Yi
DALTON TRANSACTIONS, 2017, 46 (31) : 10452 - 10461
[32] Syntheses, crystal structures, magnetic and luminescent properties of lanthanide complexes with nitronyl nitroxide radical as ligand
Wang, Shi-Yu
Wang, Wen-Min
Quan, Ying-Ping
Gao, Hong-Ling
Cui, Jian-Zhong
JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (04) : 594 - 603
[33] Syntheses and Structures of Lanthanide Complexes with Isonicotinate
ZHANG Man-Boa ZHENG Shou-Tiana YANG Guo-Yua
Chinese Journal of Structural Chemistry, 2005, (07) : 816 - 820
[34] Syntheses and Structures of Lanthanide Complexes with Isonicotinate
ZHANG ManBoa ZHENG ShouTiana YANG GuoYua b a State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China b State Key Laboratory of Coordination Chemistry Nanjing University Nanjing Jiangsu China
结构化学, 2005, (07) : 816 - 820+738
[35] A family of manganese rods:: Syntheses, structures, and magnetic properties
Rajaraman, G
Murugesu, M
Sañudo, EC
Soler, M
Wernsdorfer, W
Helliwell, M
Muryn, C
Raftery, J
Teat, SJ
Christou, G
Brechin, EK
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (47) : 15445 - 15457
[36] Syntheses and structures of lanthanide complexes with isonicotinate
Zhang, MB
Zheng, ST
Yang, GY
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (07) : 816 - 820
[37] Successive syntheses and magnetic properties of homodinuclear lanthanide macrocyclic complexes
Li, Xiang
Liu, Yu-Han
Zhu, Guang-Zhou
Yang, Feng-Lei
Gao, Feng
DALTON TRANSACTIONS, 2021, 50 (35) : 12215 - 12225
[38] Synthesis, structures and magnetic studies of hexanuclear lanthanide complexes: SMM behavior of the DyIII analogue and MCE properties of the GdIII analogue
Kumar, Pawan
Kalita, Pankaj
Palacios, Maria A.
Kumar, Vierandra
Acharya, Joydev
Colacio, Enrique
Chandrasekhar, Vadapalli
DALTON TRANSACTIONS, 2023, 52 (30) : 10594 - 10608
[39] Manganese citrate complexes: syntheses, crystal structures and thermal properties
Deng, Yuan-Fu
Zhou, Zhao-Hui
JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (05) : 778 - 788
[40] Syntheses, structures and magnetic properties of the tricyanoethenolate adducts of quadridentate Schiff base manganese(III) complexes
Sato, Y
Miyasaka, H
Matsumoto, N
Okawa, H
INORGANICA CHIMICA ACTA, 1996, 247 (01) : 57 - 63

← 1 2 3 4 5 →