Syntheses, structures, and magnetic properties of manganese-lanthanide hexanuclear complexes

被引：30
|
作者：
Shiga, Takuya [1 ]
Hoshino, Norihisa [1 ]
Nakano, Motohiro [2 ]
Nojiri, Hiroyuki [3 ]
Oshio, Hiroki [1 ]
机构：
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan
[2] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[3] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan
来源：
INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 14-15期
关键词：
magnetism; lanthanide; manganese; Schiff-base;
D O I：
10.1016/j.ica.2008.03.096
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of manganese acetate and lanthanide acetate with Schiff-base ligands (H(3)beemp = 2,6-bis[((2(2-hydroxyethoxy)ethyl)imino)methyl]-4-methylphenol) yielded hexanuclear clusters of [ Mn(4)(III)Ln(2)(III)(mu(3)-O)(2)(Hbeemp)(2)(OAc)(8)(mu(3)-OMe)(2)(H(2)O)(2)] center dot C(8)H(17)OH (Ln = Gd, Tb, and Y for 1, 2, and 3, respectively). Magnetic susceptibility measurements revealed that the mixed spin systems of 1 and 2 showed ferrimagnetic behavior, while antiferromagnetic interactions were operative among Mn(3+) ions in 3. Ac magnetic susceptibility measurements for 2 showed frequency dependent in-and out-of-phase signals, confirming slow magnetic relaxation of spin reorientations. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：4113 / 4117
页数：5
相关论文
共 50 条
  • [21] Syntheses, crystal structures, and properties of heterometallic iodoplumbates with lanthanide complexes
    Tang, Chunying
    Zheng, Wei
    Jiang, Wenqing
    Jia, Dingxian
    INORGANIC CHEMISTRY COMMUNICATIONS, 2019, 104 : 23 - 26
  • [22] Two Lanthanide Complexes with Maleichydrazide: Syntheses, Structures and Fluorescence Properties
    Deng Qing-Feng
    Yu Liang-Min
    Li Xia
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2017, 33 (09) : 1561 - 1567
  • [23] Syntheses, structures, magnetic and thermodynamics properties of tri-spin lanthanide complexes of nitronyl nitroxide
    Song, Mei-Ying
    Wen, Long-Mei
    Wang, Shu-Ping
    Yang, Shu-Tao
    Zhang, Jian-Jun
    Geng, Li-Na
    Shi, Shi-Kao
    INORGANICA CHIMICA ACTA, 2015, 430 : 1 - 7
  • [24] The Syntheses, Structures, and Magnetic Properties of Four 2D Lanthanide(III)-naphthalenedicarboxylic Complexes
    Lu, Ying-Bing
    Chen, Lei-Peng
    Zhang, Shi-Yong
    Lian, Ping
    Xie, Yong-Rong
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (14): : 2408 - 2413
  • [25] Syntheses, structures, and magnetic properties of the lanthanide complexes of imidazole-substituted nitronyl nitroxide biradicals
    Xia, Cheng-Cai
    Ji, Wen-Jie
    Zhang, Xin-Yu
    Miao, Hao
    Zhang, Yi-Quan
    Wang, Xin-Yi
    DALTON TRANSACTIONS, 2022, 51 (32) : 12362 - 12372
  • [26] Three Phenoxo-Bridged Dinuclear Lanthanide Complexes: Syntheses, Crystal Structures, and Magnetic Properties
    Zhang, Zhi-Chao
    Dai, Rui-Peng
    Dong, Hui-Ming
    Zhao, Xiao-Jun
    Yang, En-Cui
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2018, 644 (05): : 293 - 300
  • [27] Syntheses, structures and magnetic properties of a series of lanthanide complexes with reduced nitronyl nitroxide radical ligands
    Wu, Ying
    Xia, Cheng-Cai
    Wang, Xin-Yi
    INORGANICA CHIMICA ACTA, 2021, 520
  • [28] Syntheses, structures, and magnetic properties of homodinuclear lanthanide complexes based on dinucleating Schiff base ligands
    Gao, Feng
    Yang, Feng-Lei
    Zhu, Guang-Zhou
    Zhao, Yue
    DALTON TRANSACTIONS, 2015, 44 (46) : 20232 - 20241
  • [29] Syntheses, structures and magnetic properties of macrocyclic Schiff base-supported homodinuclear lanthanide complexes
    Gao, Feng
    Zhang, Yi-Quan
    Sun, Wang
    Liu, Huan
    Chen, Xiaoyu
    DALTON TRANSACTIONS, 2018, 47 (33) : 11696 - 11704
  • [30] Syntheses, structures and magnetic properties of a series of lanthanide complexes based on p-methoxybenzoic acid
    Du, Yan-Zhu
    Zheng, Ji-Min
    INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 66 : 59 - 63
12345