A perfect triangular dysprosium single-molecule magnet with virtually antiparallel Ising-like anisotropy

被引：24

作者：

Lu, Guang ^{[1
]}

Liu, Yang ^{[1
]}

Deng, Wei ^{[1
]}

Huang, Guo-Zhang ^{[1
]}

Chen, Yan-Cong ^{[1
]}

Liu, Jun-Liang ^{[1
]}

Ni, Zhao-Ping ^{[1
]}

Giansiracusa, Marcus ^{[2
]}

Chilton, Nicholas F. ^{[2
]}

Tong, Ming-Liang ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem, Minist Educ, Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China

[2] Univ Manchester, Sch Nat Sci, Dept Chem, Oxford Rd, Manchester M13 9PL, Lancs, England

来源：

INORGANIC CHEMISTRY FRONTIERS | 2020年 / 7卷 / 16期

关键词：

SPIN FRUSTRATION; GROUND-STATE; 2-STEP RELAXATION; CU(II) COMPLEXES; ION MAGNET; TRIANGLES; EXCHANGE; BEHAVIOR; LIGANDS; METAL;

D O I：

10.1039/d0qi00655f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report a trinuclear dysprosium single-molecule magnet, [Dy-3(mu(3)-CO3)((Cl)bbpen)(3)](CF3SO3)center dot 6MeCN, which has a perfectly equilateral triangular structure. The Ising-like anisotropy of each Dy(iii) site is oriented almost normal to the triangular plane, and magnetic dipole interactions between the spins cause an antiparallel Ising ground state. Crossing of the antiferromagnetic states by the ferromagnetic state occurs atca.0.2 T and gives rise to a characteristic step in magnetic hysteresis loops. This molecule thus serves as a perfectly triangular model system to explore frustrated Ising anisotropy.

引用

页码：2941 / 2948

页数：8

共 50 条

[21] Synthesis and single-molecule magnet properties of a trimetallic dysprosium metallocene cation
He, Mian
Guo, Fu-Sheng
Tang, Jinkui
Mansikkamaki, Akseli
Layfield, Richard A.
CHEMICAL COMMUNICATIONS, 2021, 57 (52) : 6396 - 6399
[22] A Discrete Dysprosium Trigonal Prism Showing Single-Molecule Magnet Behaviour
Tian, Haiquan
Wang, Min
Zhao, Lang
Guo, Yun-Nan
Guo, Yang
Tang, Jinkui
Liu, Zhiliang
CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (02) : 442 - 445
[23] Solvent Responsive Magnetic Dynamics of a Dinuclear Dysprosium Single-Molecule Magnet
Ren, Min
Bao, Song-Song
Hoshino, Norihisa
Akutagawa, Tomoyuki
Wang, Bingwu
Ding, Yu-Chen
Wei, Shiqiang
Zheng, Li-Min
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (29) : 9619 - 9628
[24] Observation of Magnetodielectric Effect in a Dysprosium-Based Single-Molecule Magnet
Wang, Yu-Xia
Ma, Yinina
Chai, Yisheng
Shi, Wei
Sun, Young
Cheng, Peng
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (25) : 7795 - 7798
[25] Observation of Magnetodielectric Effect in a Dysprosium-Based Single-Molecule Magnet
Shi, Wei (shiwei@nankai.edu.cn), 2018, American Chemical Society (140)
[26] Mapping the Magnetic Anisotropy at the Atomic Scale in Dysprosium Single-Molecule Magnets
Klahn, Emil A.
Gao, Chen
Gillon, Beatrice
Gukasov, Arsen
Fabreges, Xavier
Piltz, Ross O.
Jiang, Shang-Da
Overgaard, Jacob
CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (62) : 16576 - 16581
[27] A Mixed Porphyrin-Schiff Base Dysprosium(III) Single-Molecule Magnet
Ma, Qi
Zeng, Suyuan
Feng, Xuenan
Cao, Wei
Wang, Hailong
Dou, Jianmin
Jiang, Jianzhuang
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (26) : 4194 - 4198
[28] Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet
Guo, Fu-Sheng
Day, Benjamin M.
Chen, Yan-Cong
Tong, Ming-Liang
Mansikkamaki, Akseli
Layfield, Richard A.
SCIENCE, 2018, 362 (6421) : 1400 - +
[29] A linear tetranuclear dysprosium(III) compound showing single-molecule magnet behaviour
Ke, Hongshan
Xu, Gong-Feng
Guo, Yun-Nan
Gamez, Patrick
Beavers, Christine M.
Teat, Simon J.
Tang, Jinkui
CHEMICAL COMMUNICATIONS, 2010, 46 (33) : 6057 - 6059
[30] Coordination-perturbed single-molecule magnet behaviour of mononuclear dysprosium complexes
Chen, Gong-Jun
Gao, Chun-Yan
Tian, Jin-Lei
Tang, Jinkui
Gu, Wen
Liu, Xin
Yan, Shi-Ping
Liao, Dai-Zheng
Cheng, Peng
DALTON TRANSACTIONS, 2011, 40 (20) : 5579 - 5583

← 1 2 3 4 5 →