A linear tetranuclear dysprosium(III) compound showing single-molecule magnet behaviour

被引：100
|
作者：
Ke, Hongshan [1 ,2 ]
Xu, Gong-Feng [1 ]
Guo, Yun-Nan [1 ,2 ]
Gamez, Patrick [3 ,4 ]
Beavers, Christine M. [5 ]
Teat, Simon J. [5 ]
Tang, Jinkui [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
[4] Univ Barcelona, Dept Quim Inorgan, E-08007 Barcelona, Spain
[5] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 33期
基金：
中国国家自然科学基金;
关键词：
ANISOTROPIC BARRIER; SLOW RELAXATION; LANTHANIDE ION; SPIN; AGGREGATE; LIGAND; STATES;
D O I：
10.1039/c0cc01067g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The asymmetric Cole-Cole plots observed in a remarkable linear Dy(III) compound suggests the occurrence of multiple relaxations most likely associated with distinct anisotropic centres, thus opening new avenues for investigating the relaxation dynamics of lanthanide aggregates.
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页码：6057 / 6059
页数：3
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