A linear tetranuclear dysprosium(III) compound showing single-molecule magnet behaviour

被引：100
|
作者：
Ke, Hongshan [1 ,2 ]
Xu, Gong-Feng [1 ]
Guo, Yun-Nan [1 ,2 ]
Gamez, Patrick [3 ,4 ]
Beavers, Christine M. [5 ]
Teat, Simon J. [5 ]
Tang, Jinkui [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
[4] Univ Barcelona, Dept Quim Inorgan, E-08007 Barcelona, Spain
[5] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 33期
基金：
中国国家自然科学基金;
关键词：
ANISOTROPIC BARRIER; SLOW RELAXATION; LANTHANIDE ION; SPIN; AGGREGATE; LIGAND; STATES;
D O I：
10.1039/c0cc01067g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The asymmetric Cole-Cole plots observed in a remarkable linear Dy(III) compound suggests the occurrence of multiple relaxations most likely associated with distinct anisotropic centres, thus opening new avenues for investigating the relaxation dynamics of lanthanide aggregates.
引用
下载
收藏
页码：6057 / 6059
页数：3
相关论文
共 50 条
  • [21] Tetranuclear Dysprosium(III) Quintuple-Decker Single-Molecule Magnet Prepared Using a π-Extended Phthalocyaninato Ligand with Two Coordination Sites
    Katoh, Keiichi
    Morita, Takaumi
    Yasuda, Nobuhiro
    Wernsdorfer, Wolfgang
    Kitagawa, Yasutaka
    Breedlove, Brian K.
    Yamashita, Masahiro
    CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (58) : 15522 - 15528
  • [22] A dodecanuclear heterometallic dysprosium-cobalt wheel exhibiting single-molecule magnet behaviour
    Zou, Li-Fei
    Zhao, Lang
    Guo, Yun-Nan
    Yu, Gui-Miao
    Guo, Yang
    Tang, Jinkui
    Li, Yun-Hui
    CHEMICAL COMMUNICATIONS, 2011, 47 (30) : 8659 - 8661
  • [23] Resonant quantum tunneling in a new tetranuclear iron(III)-based single-molecule magnet
    Moragues-Cánovas, M
    Rivière, P
    Ricard, L
    Paulsen, C
    Wernsdorfer, W
    Rajaraman, G
    Brechin, EK
    Mallah, T
    ADVANCED MATERIALS, 2004, 16 (13) : 1101 - +
  • [24] Single-molecule magnet behavior in a mononuclear dysprosium(III) complex with 1-methylimidazole
    Yao, Binling
    Gu, Bin
    Su, Meihui
    Li, Guoliang
    Ma, Yue
    Li, Licun
    Wang, Qinglun
    Cheng, Peng
    Zhang, Xuan
    RSC ADVANCES, 2017, 7 (05): : 2766 - 2772
  • [25] Organophosphonate-Bridged Polyoxometalate-Based Dysprosium(III) Single-Molecule Magnet
    Huo, Yu
    Wan, Rong
    Ma, Pengtao
    Liu, Junliang
    Chen, Yancong
    Li, Dandan
    Niu, Jingyang
    Wang, Jingping
    Tong, Ming-Liang
    INORGANIC CHEMISTRY, 2017, 56 (21) : 12687 - 12691
  • [26] In situ hydrothermal synthesis of dysprosium(III) single-molecule magnet with lanthanide salt as catalyst
    Liang, Li
    Peng, Guo
    Li, Guizhu
    Lan, Yanhua
    Powell, Annie K.
    Deng, Hong
    DALTON TRANSACTIONS, 2012, 41 (19) : 5816 - 5823
  • [27] A photochromic trinuclear dysprosium(III) single-molecule magnet with two distinct relaxation processes
    Rogacz, Katarzyna
    Magott, Michal
    Bas, Sebastian
    Foltyn, Magdalena
    Rams, Michal
    Pinkowicz, Dawid
    RSC ADVANCES, 2024, 14 (21) : 14515 - 14522
  • [28] A Tetranuclear, Macrocyclic 3d-4f Complex Showing Single-Molecule Magnet Behavior
    Feltham, Humphrey L. C.
    Clerac, Rodolphe
    Powell, Annie K.
    Brooker, Sally
    INORGANIC CHEMISTRY, 2011, 50 (10) : 4232 - 4234
  • [29] Studies of a linear single-molecule magnet
    Prescimone, Alessandro
    Wolowska, Joanna
    Rajaraman, Gopalan
    Parsons, Simon
    Wernsdorfer, Wolfgang
    Murugesu, Murlaee
    Christou, George
    Piligkos, Stergios
    McInnes, Eric J. L.
    Brechin, Euan K.
    DALTON TRANSACTIONS, 2007, (45) : 5282 - 5289
  • [30] Single-molecule magnet properties of a monometallic dysprosium pentalene complex
    Kilpatrick, Alexander F. R.
    Guo, Fu-Sheng
    Day, Benjamin M.
    Mansikkamaki, Akseli
    Layfield, Richard A.
    Cloke, F. Geoffrey N.
    CHEMICAL COMMUNICATIONS, 2018, 54 (51) : 7085 - 7088
12345