Self-condensation reactions of acyl phosphonates: synthesis of tertiary O-protected α-hydroxyphosphonates

被引：2

作者：

Eymur, Serkan ^{[1
,2
]}

Gollu, Mehmet ^{[2
]}

Demir, Ayhan Sitki ^{[2
]}

机构：

[1] Selcuk Univ, Dept Chem, Konya, Turkey

[2] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 01期

关键词：

Acyl phosphonates; tertiary alpha-hydroxy phosphonates; phosphonate-phosphate rearrangement; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; HYDROXY PHOSPHONATES; ANION EQUIVALENTS; DERIVATIVES; INHIBITORS; STATE; ACYLPHOSPHONATES; OXIDATION;

D O I：

10.3906/kim-1306-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-condensation reaction of benzoyl dialkyl phosphonates was developed using cyanide ion as catalyst, affording versatile tertiary O-protected alpha-hydroxy phosphonates in moderate yield.

引用

页码：164 / 171

页数：8

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