Self-condensation reactions of acyl phosphonates: synthesis of tertiary O-protected α-hydroxyphosphonates

被引：2
|
作者：
Eymur, Serkan [1 ,2 ]
Gollu, Mehmet [2 ]
Demir, Ayhan Sitki [2 ]
机构：
[1] Selcuk Univ, Dept Chem, Konya, Turkey
[2] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
来源：
TURKISH JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 01期
关键词：
Acyl phosphonates; tertiary alpha-hydroxy phosphonates; phosphonate-phosphate rearrangement; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; HYDROXY PHOSPHONATES; ANION EQUIVALENTS; DERIVATIVES; INHIBITORS; STATE; ACYLPHOSPHONATES; OXIDATION;
D O I：
10.3906/kim-1306-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The self-condensation reaction of benzoyl dialkyl phosphonates was developed using cyanide ion as catalyst, affording versatile tertiary O-protected alpha-hydroxy phosphonates in moderate yield.
引用
收藏
页码：164 / 171
页数：8
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