Corrosion Behaviour of 316L Stainless Steel in Hot Dilute Sulphuric Acid Solution with Sulphate and NaCl

被引:8
|
作者
Zhang, Jian [1 ]
Ju, Pengfei [2 ]
Wang, Chaoli [1 ]
Dun, Yuchao [1 ]
Zhao, Xuhui [1 ]
Zuo, Yu [1 ]
Tang, Yuming [1 ]
机构
[1] Beijing Univ Chem Technol, Key Lab Electrochem Proc & Technol Mat, Beijing 100029, Peoples R China
[2] Shanghai Aerosp Equipment Manufacture Co Ltd, Shanghai 200245, Peoples R China
基金
中国国家自然科学基金;
关键词
316L SS; hot dilute sulphuric acid; corrosion; sodium chloride; sodium sulphate; corrosion products; PITTING CORROSION; SINGLE PIT; CHLORIDE; TEMPERATURE; INITIATION; GROWTH; IONS; DISSOLUTION; CHROMIUM; AISI-304;
D O I
10.1134/S207020511901026X
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The corrosion behaviour of 316L stainless steel (316L SS) in 10% H2SO4 solution (94 degrees C) with various concentrations of NaCl (0-0.085 mol/L) was studied by immersion corrosion test and polarization methods, combined with SEM/EDS, XPS and XRD tests. The influence of NaCl on the corrosion of 316L SS was investigated. The results showed that at lower NaCl contents (0-0.0085 mol/L), the steel presented a general corrosion characteristic with a higher corrosion speed and the corrosion rate increased with the NaCl content. At higher NaCl contents (0.017 mol/L), the corrosion rate decreased remarkably due to the protective corrosion products precipitation which contained metallic sulphates and NaHSO4. However, the higher concentration of chloride ions caused micron pitting-like local dissolution on the surface. The addition of Na2SO4 effectively inhibited general corrosion of the steel because of a dense and continuous products layer enriched with more NaHSO4 and metallic sulphates formed.
引用
收藏
页码:148 / 156
页数:9
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