Palladium-Catalyzed Suzuki Reaction in Aqueous Media

被引：16
|
作者：
Liu, Ning [1 ]
Liu, Chun [1 ]
Jin, Zilin [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 32卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Suzuki reaction; palladium catalyst; aqueous phase; CROSS-COUPLING REACTIONS; MICROWAVE-ASSISTED SUZUKI; N-HETEROCYCLIC CARBENES; LIGAND-FREE PALLADIUM; MIYAURA REACTION; ARYL CHLORIDES; ARYLBORONIC ACIDS; HIGHLY EFFICIENT; RECYCLABLE CATALYST; HECK REACTIONS;
D O I：
10.6023/cjoc1109052
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The palladium-catalyzed Suzuki cross-coupling reaction has become one of the most powerful tools for sp(2)-sp(2) carbon-carbon bond formation. This coupling reaction is increasingly being applied in the synthesis of pharmaceuticals, natural products and advanced functional materials. In recent years, developing aqueous systems for the Suzuki reaction has attracted attention from many researchers. This paper reviews the recent progress in the Suzuki reaction using neat water and aqueous-organic co-solvent as reaction media. A large number of different strategies for the Suzuki reaction in water have been developed, in which the authors aim at the solutions to the enhancement of the reactivity of the palladium-catalyzed Suzuki reaction using water-soluble ligands, surfactants, microwave assistance, or ligand-free system.
引用
收藏
页码：860 / 876
页数：17
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