Synthesis and crystal structure of a new N-alkylated azacrown ligand and its copper(II) complex

被引：2
|
作者：
Xu, XY [1 ]
Ma, WX [1 ]
Wang, ZL [1 ]
Luo, QH [1 ]
Ni, SS [1 ]
Zhou, XG [1 ]
Zhou, ZY [1 ]
机构：
[1] CHINESE ACAD SCI,CHENGDU INST ORGAN CHEM,CHENGDU 610041,PEOPLES R CHINA
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 07期
关键词：
D O I：
10.1080/00945719708000247
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new pendant-arm macrocyclic ligand, N,N'-bis(2-cyanoethyl)-3,4:9, 10-dibenzol, 12-diaza-5, 8-dioxacyclopentadecane (L), was synthesized in 93% yield by alkylating 3,4:9,10-dibenzo-1,12-diaza-5,8-dioxacyclopentadecane with acrylonitrile. Its crystal structure was determined and its copper(II) complex was also prepared. All compounds were characterized by IR, NMR, elemental analyses and UV-Vis. The complex has the formula of CuLCl2 . 2H(2)O.
引用
收藏
页码：1059 / 1069
页数：11
相关论文
共 50 条
  • [41] New Asymmetric Iminophosphonamide Ligand and Its Yttrium Complex: Synthesis and Crystal Structure
    Sinitsa, D. K.
    Sukhikh, T. S.
    Pushkarevsky, N. A.
    Konchenko, S. N.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2024, 65 (04) : 666 - 675
  • [42] Synthesis and crystal structure of mononuclear copper(II) complex of tridentate Schiff base ligand and its ferrocyanide-bridged pentanuclear complex
    Mondal, N
    Saha, MK
    Bag, B
    Mitra, S
    Rosair, G
    El Fallah, MS
    POLYHEDRON, 2001, 20 (7-8) : 579 - 584
  • [43] Synthesis and crystal structure of a tetraazamacrocyclic copper(II) complex
    Bi, Jian-Hong
    Tao, Wen-Bo
    Huang, Zi-Xiang
    Bi, Wen-Tao
    ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (08) : 6618 - 6620
  • [44] Synthesis and Crystal Structure of a Mononuclear Copper(II) Complex
    Zhang, Hong-Ge
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (15) : 8597 - 8599
  • [45] Stereochemistry of complexes with N-alkylated amino acids .9. Crystal structure and conformational analysis of aquabis (L-N-benzylalaninato)copper(II) monohydrate
    Kaitner, B
    Mestrovic, E
    Paulic, N
    Raos, N
    JOURNAL OF COORDINATION CHEMISTRY, 1995, 34 (01) : 55 - 66
  • [46] Synthesis and crystal structure of binuclear copper (II) complex
    Yang, RN
    Sun, YA
    Hu, XY
    Xue, BY
    Jin, DM
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 1999, 15 (03) : 357 - 362
  • [47] Synthesis and Crystal Structure of the Azo Copper(II)-complex
    Ren Yue-Hong
    Dong Jin-Long
    Wang Zi-Wei
    Ren Jian-Guo
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 30 (03) : 376 - 379
  • [48] Synthesis, crystal structures and magnetic properties of a radical ligand and its corresponding copper(II) complex
    Wang, Yu-Fang
    Wang, Li-Ya
    TRANSITION METAL CHEMISTRY, 2010, 35 (05) : 591 - 595
  • [49] Synthesis, crystal structures and magnetic properties of a radical ligand and its corresponding copper(II) complex
    Yu-Fang Wang
    Li-Ya Wang
    Transition Metal Chemistry, 2010, 35 : 591 - 595
  • [50] Synthesis and Crystal Structure of a Copper(II) Complex with 2,4-Dihydroxybenzylidene Benzoylhydrazone Ligand
    卢文贯
    刘宏文
    Chinese Journal of Structural Chemistry, 2005, (09) : 1078 - 1082
12345