Synthesis and crystal structure of a new N-alkylated azacrown ligand and its copper(II) complex

被引：2
|
作者：
Xu, XY [1 ]
Ma, WX [1 ]
Wang, ZL [1 ]
Luo, QH [1 ]
Ni, SS [1 ]
Zhou, XG [1 ]
Zhou, ZY [1 ]
机构：
[1] CHINESE ACAD SCI,CHENGDU INST ORGAN CHEM,CHENGDU 610041,PEOPLES R CHINA
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 07期
关键词：
D O I：
10.1080/00945719708000247
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new pendant-arm macrocyclic ligand, N,N'-bis(2-cyanoethyl)-3,4:9, 10-dibenzol, 12-diaza-5, 8-dioxacyclopentadecane (L), was synthesized in 93% yield by alkylating 3,4:9,10-dibenzo-1,12-diaza-5,8-dioxacyclopentadecane with acrylonitrile. Its crystal structure was determined and its copper(II) complex was also prepared. All compounds were characterized by IR, NMR, elemental analyses and UV-Vis. The complex has the formula of CuLCl2 . 2H(2)O.
引用
收藏
页码：1059 / 1069
页数：11
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