Mono lacunary phosphotungstate anchored to MCM-41 as recyclable catalyst for biodiesel production via transesterification of waste cooking oil

被引：28
|
作者：
Singh, Sukriti [1 ]
Patel, Anjali [1 ]
机构：
[1] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Chem, Polyoxometalates & Catalysis Lab, Vadodara 390002, Gujarat, India
来源：
FUEL | 2015年 / 159卷
关键词：
Mono lacunary phosphotungstate; MCM-41; Biodiesel; Waste cooking oil; Kinetics; SOLID ACID CATALYSTS; FREE FATTY-ACID; OLEIC-ACID; SUPPORTED UNDECATUNGSTOPHOSPHATE; HETEROGENEOUS CATALYSTS; ESTERIFICATION; PERFORMANCE; CHEMISTRY; OXIDATION; WELL;
D O I：
10.1016/j.fuel.2015.07.004
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Mono lacunary phosphotungstate (PW11) anchored to MCM-41 was synthesized and characterized by various physicochemical techniques. Preliminary studies for biodiesel production by esterification of oleic acid was carried out and study was further extended to transesterification of waste cooking oil. The Kinetic study reveals that the reactions follow first order kinetics and activation energy for transesterification was 64.1 kJ/mol. The present catalyst can be recycled without any significant change in % conversion. The high activity of this new catalyst for transesterification reactions suggests an alternative path as well as reduction in cost for the production of biodiesel under mild reaction conditions. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：720 / 727
页数：8
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