Mono lacunary phosphotungstate anchored to MCM-41 as recyclable catalyst for biodiesel production via transesterification of waste cooking oil

被引：28
|
作者：
Singh, Sukriti [1 ]
Patel, Anjali [1 ]
机构：
[1] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Chem, Polyoxometalates & Catalysis Lab, Vadodara 390002, Gujarat, India
来源：
FUEL | 2015年 / 159卷
关键词：
Mono lacunary phosphotungstate; MCM-41; Biodiesel; Waste cooking oil; Kinetics; SOLID ACID CATALYSTS; FREE FATTY-ACID; OLEIC-ACID; SUPPORTED UNDECATUNGSTOPHOSPHATE; HETEROGENEOUS CATALYSTS; ESTERIFICATION; PERFORMANCE; CHEMISTRY; OXIDATION; WELL;
D O I：
10.1016/j.fuel.2015.07.004
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Mono lacunary phosphotungstate (PW11) anchored to MCM-41 was synthesized and characterized by various physicochemical techniques. Preliminary studies for biodiesel production by esterification of oleic acid was carried out and study was further extended to transesterification of waste cooking oil. The Kinetic study reveals that the reactions follow first order kinetics and activation energy for transesterification was 64.1 kJ/mol. The present catalyst can be recycled without any significant change in % conversion. The high activity of this new catalyst for transesterification reactions suggests an alternative path as well as reduction in cost for the production of biodiesel under mild reaction conditions. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：720 / 727
页数：8
相关论文
共 50 条
  • [21] Biodiesel production from waste cooking oil via alkali catalyst and its engine test
    Meng, Xiangmei
    Chen, Guanyi
    Wang, Yonghong
    FUEL PROCESSING TECHNOLOGY, 2008, 89 (09) : 851 - 857
  • [22] Anchored palladium bipyridyl complex in nanosized MCM-41: a recyclable and efficient catalyst for the Kumada-Corriu reaction
    Tsai, Fu-Yu
    Lin, Bo-Nan
    Chen, Ming-Jie
    Mou, Chung-Yuan
    Liu, Shiuh-Tzung
    TETRAHEDRON, 2007, 63 (20) : 4304 - 4309
  • [23] Biodiesel Production from Waste Cooking Oil Catalyzed by a Bifunctional Catalyst
    Enguilo Gonzaga, Vania
    Romero, Rubi
    Maria Gomez-Espinosa, Rosa
    Romero, Amaya
    Luz Martinez, Sandra
    Natividad, Reyna
    ACS OMEGA, 2021, 6 (37): : 24092 - 24105
  • [24] Biodiesel Production From Waste Cooking Oil using Homogeneous Catalyst
    Hamed, Hussein H.
    Mohammed, Awad E.
    Habeeb, Omar Abed
    Ali, Obed M.
    Aljaf, Omar Hama Salih
    Abdulqader, Mahmod A.
    EGYPTIAN JOURNAL OF CHEMISTRY, 2021, 64 (06): : 2827 - 2832
  • [25] Using Response Surface Methodology in Optimisation of Biodiesel Production via Alkali Catalysed Transesterification of Waste Cooking Oil
    Naidoo, R.
    Sithole, B.
    Obwaka, E.
    JOURNAL OF SCIENTIFIC & INDUSTRIAL RESEARCH, 2016, 75 (03): : 188 - 193
  • [26] Transesterification of waste cooking oil for biodiesel production using alkaline-modified graphitic carbon nitride heterogeneous catalyst
    Monika, Vinayak V.
    Pathak, Vinayak V.
    Banga, Sangita
    ENVIRONMENTAL TECHNOLOGY, 2024,
  • [27] Characterization and parametric study of mesoporous calcium titanate catalyst for transesterification of waste cooking oil into biodiesel
    Yahya, Noor Yahida
    Ngadi, Norzita
    Jusoh, Mazura
    Halim, Noor Amirah Abdul
    ENERGY CONVERSION AND MANAGEMENT, 2016, 129 : 275 - 283
  • [28] Utilization of waste coral for biodiesel production via transesterification of soybean oil
    G. Moradi
    F. Mohammadi
    International Journal of Environmental Science and Technology, 2014, 11 : 805 - 812
  • [29] Utilization of waste coral for biodiesel production via transesterification of soybean oil
    Moradi, G.
    Mohammadi, F.
    INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2014, 11 (03) : 805 - 812
  • [30] Surfactant containing Ca/MCM-41 as a highly active, green and reusable catalyst for the transesterification of canola oil
    Pirouzmand, Mahtab
    Nikzad-Kojanag, Behnaz
    Seyed-Rasulzade, S. Keyvan
    CATALYSIS COMMUNICATIONS, 2015, 69 : 196 - 201
12345