Iridium(I)-catalyzed vinylic C-H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron

被引：25
|
作者：
Sasaki, Ikuo [1 ]
Doi, Hana [1 ]
Hashimoto, Toshiya [1 ]
Kikuchi, Takao [1 ]
Ito, Hajime [1 ]
Ishiyama, Tatsuo [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Engn, Div Chem Proc Engn, Sapporo, Hokkaido 0608628, Japan
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 68期
关键词：
CATALYZED DEHYDROGENATIVE BORYLATION; CROSS-COUPLING REACTION; ROOM-TEMPERATURE REACTIONS; EFFICIENT SYNTHESIS; 1-ALKENYL HALIDES; ALKENES; ARENES; ACTIVATION; FUNCTIONALIZATION; COMPLEXES;
D O I：
10.1039/c3cc44149k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ir(I)-catalyzed C-H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki-Miyaura cross-coupling procedure.
引用
收藏
页码：7546 / 7548
页数：3
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