Iridium(I)-catalyzed vinylic C-H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron

被引：25

作者：

Sasaki, Ikuo ^{[1
]}

Doi, Hana ^{[1
]}

Hashimoto, Toshiya ^{[1
]}

Kikuchi, Takao ^{[1
]}

Ito, Hajime ^{[1
]}

Ishiyama, Tatsuo ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Chem Proc Engn, Sapporo, Hokkaido 0608628, Japan

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 68期

关键词：

CATALYZED DEHYDROGENATIVE BORYLATION; CROSS-COUPLING REACTION; ROOM-TEMPERATURE REACTIONS; EFFICIENT SYNTHESIS; 1-ALKENYL HALIDES; ALKENES; ARENES; ACTIVATION; FUNCTIONALIZATION; COMPLEXES;

D O I：

10.1039/c3cc44149k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ir(I)-catalyzed C-H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki-Miyaura cross-coupling procedure.

引用

页码：7546 / 7548

页数：3

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