Synthesis and structural characterization of new one-dimensional rhodium complexes

被引：34

作者：

Pruchnik, FP ^{[1
]}

Jakimowicz, P ^{[1
]}

Ciunik, Z ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 12期

关键词：

metal wires; nitrogen heterocycles; N ligands; rhodium; stacking interactions;

D O I：

10.1016/S1387-7003(01)00314-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New one-dimensional Rh-I-Rh-II complexes [Rh-2(OOCMe)(2)(phen)(2)](n)(PF6)(n)(.)0.5nMe(2)CHOH, 1 and [Rh-2(OOCMe)(2)(bpy)(2)](n) (PF6)(n) (.) nH(2)O, 2 have been synthesized and characterized. The compound 1 is molecular wire with the shortest Rh(I)-Rh(II) distances, anions and solvate molecules occupy channels between parallel cationic wires. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：726 / 729

页数：4

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