Synthesis and structural characterization of new one-dimensional rhodium complexes

被引：34
|
作者：
Pruchnik, FP [1 ]
Jakimowicz, P [1 ]
Ciunik, Z [1 ]
机构：
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 12期
关键词：
metal wires; nitrogen heterocycles; N ligands; rhodium; stacking interactions;
D O I：
10.1016/S1387-7003(01)00314-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New one-dimensional Rh-I-Rh-II complexes [Rh-2(OOCMe)(2)(phen)(2)](n)(PF6)(n)(.)0.5nMe(2)CHOH, 1 and [Rh-2(OOCMe)(2)(bpy)(2)](n) (PF6)(n) (.) nH(2)O, 2 have been synthesized and characterized. The compound 1 is molecular wire with the shortest Rh(I)-Rh(II) distances, anions and solvate molecules occupy channels between parallel cationic wires. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：726 / 729
页数：4
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