Ni-Catalyzed Direct Carboxylation of Benzyl Halides with CO2

被引：254
|
作者：
Leon, Thierry [1 ]
Correa, Arkaitz [1 ]
Martin, Ruben [1 ]
机构：
[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 04期
基金：
欧洲研究理事会;
关键词：
FUNCTIONALIZED ORGANOZINC REAGENTS; C-H BONDS; CARBON-DIOXIDE; ARYL HALIDES; ALKYL-HALIDES; CARBONYLATION; ACID; ALDEHYDES; CHLORIDES; COMPLEX;
D O I：
10.1021/ja311045f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel Ni-catalyzed carboxylation of benzyl halides with CO2 has been developed. The described carboxylation reaction proceeds under mild conditions (atmospheric CO, pressure) at room temperature. Unlike other routes for similar means, our method does not require well-defined and sensitive organometallic reagents and thus is a user-friendly and operationally simple protocol for assembling phenylacetic acids.
引用
收藏
页码：1221 / 1224
页数：4
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