Adsorption structure of 1,3-butadiene on Pd(110)

被引：21
|
作者：
Katano, S
Ichihara, S
Ogasawara, H
Kato, HS
Komeda, T
Kawai, M
Domen, K
机构：
[1] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan
[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
来源：
SURFACE SCIENCE | 2002年 / 502卷
关键词：
electron energy loss spectroscopy (EELS); near edge extended X-ray absorption fine structure (NEXAFS); scanning tunneling microscopy; palladium; chemisorption; adsorption kinetics;
D O I：
10.1016/S0039-6028(01)01928-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Adsorption structure of 1,3-butadiene chemisorbed on Pd(110) has been studied by high resolution electron energy loss spectroscopy (HREELS). near edge X-ray absorption fine structure (NEXAFS), and scanning tunneling microscopy (STM). The HREELS and NEXAFS results revealed that 1,3-butadiene is adsorbed with pi-bond and the molecular plane is parallel to the surface, in which the C-C single bond in 1,3-butadiene on Pd(110) is aligned toward [1 (1) over bar0]. The adsorption site and geometry were determined oil the basis of the STM image analysis. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：164 / 168
页数：5
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