Adsorption structure of 1,3-butadiene on Pd(110)

被引：21
|
作者：
Katano, S
Ichihara, S
Ogasawara, H
Kato, HS
Komeda, T
Kawai, M
Domen, K
机构：
[1] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan
[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
来源：
SURFACE SCIENCE | 2002年 / 502卷
关键词：
electron energy loss spectroscopy (EELS); near edge extended X-ray absorption fine structure (NEXAFS); scanning tunneling microscopy; palladium; chemisorption; adsorption kinetics;
D O I：
10.1016/S0039-6028(01)01928-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Adsorption structure of 1,3-butadiene chemisorbed on Pd(110) has been studied by high resolution electron energy loss spectroscopy (HREELS). near edge X-ray absorption fine structure (NEXAFS), and scanning tunneling microscopy (STM). The HREELS and NEXAFS results revealed that 1,3-butadiene is adsorbed with pi-bond and the molecular plane is parallel to the surface, in which the C-C single bond in 1,3-butadiene on Pd(110) is aligned toward [1 (1) over bar0]. The adsorption site and geometry were determined oil the basis of the STM image analysis. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：164 / 168
页数：5
相关论文
共 50 条
  • [21] Dimer of Pd(II) β-Octaethylporphyrin Bound by a 1,3-Butadiene Bridge
    Orlova, Ekaterina A.
    Romanenko, Yuliya, V
    Tyurin, Vladimir S.
    Shkirdova, Alena O.
    Belyaev, Evgeny S.
    Grigoriev, Mikhail S.
    Koifman, Oskar I.
    Zamilatskov, Ilya A.
    [J]. MACROHETEROCYCLES, 2022, 15 (03): : 139 - 146
  • [22] THE ORIENTATION AND ELECTRONIC-STRUCTURE OF 1,3-BUTADIENE ADSORBED AND CONDENSED ON AG(110) - A NEXAFS STUDY
    COULMAN, D
    SOLOMON, JL
    MADIX, RJ
    STOHR, J
    [J]. SURFACE SCIENCE, 1991, 257 (1-3) : 97 - 102
  • [23] 1,3-DIPHOSPHA-1,3-BUTADIENE
    APPEL, R
    FOLLING, P
    SCHUHN, W
    KNOCH, F
    [J]. TETRAHEDRON LETTERS, 1986, 27 (15) : 1661 - 1664
  • [24] ADSORPTION OF 2-METHYLPROPENE AND 1,3-BUTADIENE ON ACTIVATED CARBON
    OLIVIER, MG
    BERLIER, K
    BOUGARD, J
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (04): : 774 - 776
  • [25] Propyne and 1,3-butadiene adsorption and co-adsorption over palladium catalysts
    Sh. Burns
    S. D. Jackson
    E. M. Vass
    [J]. Kinetics and Catalysis, 2011, 52 : 723 - 732
  • [26] Propyne and 1,3-butadiene adsorption and co-adsorption over palladium catalysts
    Burns, Sh.
    Jackson, S. D.
    Vass, E. M.
    [J]. KINETICS AND CATALYSIS, 2011, 52 (05) : 723 - 732
  • [27] Structure of the high-energy conformer of 1,3-butadiene
    DeMare, GR
    Panchenko, YN
    VanderAuwera, J
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (22): : 3998 - 4004
  • [28] 1-CYANO-1,3-BUTADIENE .3. THE DIMER OF 1-CYANO-1,3-BUTADIENE
    SNYDER, HR
    POOS, GI
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (04) : 1395 - 1396
  • [29] AN ELECTRON DIFFRACTION REINVESTIGATION OF THE MOLECULAR STRUCTURE OF 1,3-BUTADIENE
    ALMENNINGEN, A
    BASTIANSEN, O
    TRAETTEBERG, M
    [J]. ACTA CHEMICA SCANDINAVICA, 1958, 12 (06): : 1221 - 1225
  • [30] TRANS-1-PHENYL-1,3-BUTADIENE - 1,3-BUTADIENE, 1-PHENYL, TRANS-
    GRUMMITT, O
    BECKER, EI
    [J]. ORGANIC SYNTHESES, 1950, 30 : 75 - 79
12345