Gas Desorption Characteristics of the Chang 7 Member Shale in the Triassic Yanchang Formation, Yan'an Area, Ordos Basin

In the Yan'an area of the Ordos Basin, the lithological heterogeneity of Chang 7 Member shale is extremely strong. In addition, sandy laminae is highly developed within the Chang 7 Member shale system. In order to explore the gas generation and migration processes of Chang 7 Member shale, geochemical characteristics of desorption gas are comprehensively compared and analyzed. In this study, rock crushing experiments were carried out to obtain shale samples, and desorption experiments were carried out to obtain shale samples and sandy laminated shale samples. For the crushing gas and desorption gas, the volume contents of different gas components were obtained using gas chromatography experiments. The rock crushing experiments revealed that the average volume percentage of CH4 in Chang 7 Member shale is 61.93%, the average volume percentage of C2H6 and C3H8 is 29.53%, and the average volume percentage of other gases is relatively small. The shale gas in Chang 7 Member is wet gas; the gas is kerogen pyrolysis gas. Most of the shale gas hosting in Chang 7 Member shale is adsorbed gas. Porosity, permeability and organic matter content are the main geological factors controlling gas migration and gas hosting. Shale with a higher porosity, good permeability and a low organic matter content is conducive to gas migration. The shale gas in Chang 7 Member shale contains CH4, C2H6, C3H8, iC(4)H(10), nC(4)H(10), iC(5)H(12), nC(5)H(12), CO2 and N-2. N-2 migrates more easily than CH4, and CH4 migrates more easily than CO2. For hydrocarbon gases, gas components with small molecular diameters are easier to migrate. The desorption characteristics of shale might provide clues for guiding hydrocarbon exploration in the study area. The sandy laminated shale with a higher gas content may be the "sweet spot" of shale gas targets. In Chang 7 Member, the locations hosting both shale oil and CH4 may be the most favorable targets for shale oil production.