Metal-promoted synthetic chemistry within living cells

被引：11

作者：

Miguel-Avila, Joan ^{[1
,2
]}

Tomas-Gamasa, Maria ^{[1
,2
]}

Mascarenas, Jose L. ^{[1
,2
]}

机构：

[1] Univ Santiago De Compostela, Ctr Singular Invest Quim Biolox Mat Mol CIQUS, Santiago De Compostela 15782, Spain

[2] Univ Santiago De Compostela, Dept Quim Organ, Santiago De Compostela 15782, Spain

来源：

TRENDS IN CHEMISTRY | 2023年 / 5卷 / 06期

关键词：

SELECTIVE FLUORESCENT-PROBE; BIOORTHOGONAL CATALYSIS; TRANSFER HYDROGENATION; PROTEINS;

D O I：

10.1016/j.trechm.2023.04.001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ability to perform 'new-to-nature' chemical reactions within living cells and organisms is transforming the way in which scientists interrogate and/or manip-ulate biological processes. In recent years, the toolbox of bioorthogonal and cell -compatible reactions has been enriched with the incorporation of transition metal-mediated processes. Whereas the efficiency of these reactions is still low, the breadth and generality of organometallic catalysis promises to signifi-cantly impact the field of bioorthogonal chemistry. Particularly attractive is the possibility of using organometallic catalysis for performing bond-forming, syn-thetically relevant reactions, as this could allow assembly of biorelevant prod-ucts at specific biological sites.

引用

页码：474 / 485

页数：12

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