Role of copper in the stereoselective metal-promoted cyclotrimerisation of polycyclic alkenes

被引：0
|
作者：
Peluso, P [1 ]
De Lucchi, O [1 ]
Cossu, S [1 ]
机构：
[1] Univ Ca Foscari Venezia, Dipartimento Chim, I-30123 Venice, Italy
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 2002卷 / 23期
关键词：
copper; cross-coupling; molecular discrimination; cyclization; alkenes;
D O I：
10.1002/1099-0690(200212)2002:23<4032::AID-EJOC4032>3.0.CO;2-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Copper-mediated stereoselective cyclotrimerisation of polycyclic alkenes is reported. The mechanism involved provides strong support for the involvement of a Cull, intermediate in cross-coupling reactions of sp(2)-carbon atoms. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2002).
引用
收藏
页码：4032 / 4036
页数：5
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