Microwave-enhanced selective leaching calcium from steelmaking slag to fix CO2 and produce high value-added CaCO3

The abundant resources of steel slag make it an intriguing prospect for long-term CO2 storage by mineral carbonation. Herein, the dissolution of steel slag in an acetic acid (HAc) solution and the fixation of CO2 in the leachate of steel slag to synthesize high-value CaCO3 were investigated. Results show that the microwave water bath condition is beneficial for improving the leaching rate of Ca and Mg elements in steel slag, while the low-concentration HAc solution displays high selectivity for Ca + Mg. In a water bath reaction enhanced by microwave, the leaching rate and selectivity of Ca + Mg can be increased by elevating the reaction temperature, extending the leaching time, lowering the concentration of HAc solution, and increasing the stirring rate. The kinetic parameters of the calcium element, including the apparent activation energy, were determined to be 14.51 kJ & sdot;mol- 1, suggesting control by surface chemical reactions. Finally, high-purity CaCO3 crystal whiskers can be synthesized under 400 W ultrasonic conditions with a reaction temperature of 70 degrees C, reaction time of 15 min, and a solution pH at 9.1 by introducing 20 % CO2 into the leachate. This strategy facilitates the concurrent utilization of dilute CO2 flue gas and voluminous solid steel slag waste, thereby improving the economic and environmental performance of the steel industry.