C-H functionalization with alkenes, allenes, and alkynes by half- sandwich rare-earth catalysts

被引：29

作者：

Cong, Xuefeng ^{[1
]}

Huang, Lin ^{[1
]}

Hou, Zhaomin ^{[1
,2
]}

机构：

[1] RIKEN Ctr Sustainable Resource Sci, Adv Catalysis Res Grp, 2-1 Hirosawa, Wako, Saitama 3510198, Japan

[2] RIKEN Cluster Pioneering Res, Organometall Chem Lab, 2-1 Hirosawa, Wako, Saitama 3510198, Japan

来源：

TETRAHEDRON | 2023年 / 135卷

关键词：

C-H activation; Asymmetric catalysis; C-C bond Formation; Half-sandwich rare-earth catalyst; Annulation; TERMINAL ALKYNES; AROMATIC IMINES; BOND ADDITION; STYRENE POLYMERIZATION; OLEFIN POLYMERIZATION; INTERMOLECULAR 2+2; METHYL SULFIDES; METAL COMPLEXES; SCANDIUM; ALKYLATION;

D O I：

10.1016/j.tet.2023.133323

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalytic C-H activation and transformation has received tremendous attention. This Perspective focuses on recent advances in C-H functionalization with alkenes, allenes, and alkynes by half-sandwich rare-earth catalysts, including asymmetric transformations. The reaction generally proceeds through formal C-H addition to unsaturated C-C bonds, thus constituting a 100% atom-efficient route for the con-struction of new C-C bonds. Future outlooks in related areas are also described. (c) 2023 Elsevier Ltd. All rights reserved.

引用

页数：16

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